Characteristics of Rhombohedral (3R) Structure of α-In2Se3 Nanosheets by Mechanical Exfoliation

IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Dong Hyun Seo, Ju Won Kim, Jin-Hoo Seong, Hyo-Chang Lee, Sang-il Kim, TaeWan Kim
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Abstract

The mechanically exfoliated ultrathin 3R α-In2Se3 nanosheets were transferred onto a SiO2/Si substrate. Using atomic force microscopy, it was confirmed that the transferred α-In2Se3 transferred had a thickness of 15–120 nm. The thickness-dependence of Raman peaks of \({E}^{2}\), \({A}_{1}^{1}\), \({E}^{4}\), and \({A}_{1}^{2}\) was observed from the Raman spectra. Moreover, the measured photoluminescence peak values in the range of 869–895 nm indicate a blue shift as the thickness decreases. The field-effect transistor based on α-In2Se3 exhibited an n-type semiconductor behavior. From the transfer curve at gate voltage of 10 V, the derived values of the mobility and ON/OFF ratio are 24.26 cm2 V− 1 s− 1 and 1.84, respectively. In addition, it was confirmed that the 3R α-In2Se3 layers had a high photoresponsivity of up to approximately 34,500 A/W under illumination (\(\lambda\) = 750 nm).

Graphical abstract

Abstract Image

机械剥离法制备α-In2Se3纳米片的菱形(3R)结构特征
机械剥离的超薄 3R α-In2Se3 纳米片被转移到二氧化硅/硅衬底上。使用原子力显微镜证实,转移的 α-In2Se3 厚度为 15-120 nm。从拉曼光谱中观察到了\({E}^{2}\)、\({A}_{1}^{1}\)、\({E}^{4}\)和\({A}_{1}^{2}\)拉曼峰的厚度依赖性。此外,在 869-895 nm 范围内测得的光致发光峰值表明,随着厚度的减小,光致发光会发生蓝移。基于 α-In2Se3 的场效应晶体管表现出 n 型半导体特性。根据栅极电压为 10 V 时的转移曲线,得出的迁移率和导通/关断比值分别为 24.26 cm2 V- 1 s- 1 和 1.84。此外,研究还证实 3R α-In2Se3 层在光照(\(\lambda\) = 750 nm)下具有高达约 34,500 A/W 的光致发光率。
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来源期刊
Electronic Materials Letters
Electronic Materials Letters 工程技术-材料科学:综合
CiteScore
4.70
自引率
20.80%
发文量
52
审稿时长
2.3 months
期刊介绍: Electronic Materials Letters is an official journal of the Korean Institute of Metals and Materials. It is a peer-reviewed international journal publishing print and online version. It covers all disciplines of research and technology in electronic materials. Emphasis is placed on science, engineering and applications of advanced materials, including electronic, magnetic, optical, organic, electrochemical, mechanical, and nanoscale materials. The aspects of synthesis and processing include thin films, nanostructures, self assembly, and bulk, all related to thermodynamics, kinetics and/or modeling.
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