{"title":"Linking impact melt redox with crustal weathering regime","authors":"B. Black, M. Brounce","doi":"10.1130/g51405.1","DOIUrl":null,"url":null,"abstract":"Impact melting and outgassing of impact melts were important processes shaping the crust and atmosphere of early Earth and Mars. The redox state of impact melts influences the gases they release, but the controls on impact melt redox are not well understood. Here, we present Fe micro−X-ray absorption near edge structure (μ-XANES) measurements of a suite of impact melt glasses from Lonar crater, India. As an impact into continental flood basalts, Lonar crater is an ideal analog for impacts into basaltic crust on early Earth and Mars. The Fe-μ-XANES technique permits robust characterization of the Fe3+/ΣFe ratio and therefore redox conditions in Lonar glasses. We found a range in Fe3+/ΣFe of 0.21−0.49 among Lonar glasses, including substantial intraclast variations. We conclude that a primary factor driving these variations was pre-impact oxidative weathering of target rocks. The coupling between crustal weathering regime and speciation of gases released from impact melts implies that impact melt outgassing could act as a feedback mechanism to reinforce prevailing surface redox conditions.","PeriodicalId":12642,"journal":{"name":"Geology","volume":" ","pages":""},"PeriodicalIF":4.8000,"publicationDate":"2023-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Geology","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.1130/g51405.1","RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOLOGY","Score":null,"Total":0}
引用次数: 0
Abstract
Impact melting and outgassing of impact melts were important processes shaping the crust and atmosphere of early Earth and Mars. The redox state of impact melts influences the gases they release, but the controls on impact melt redox are not well understood. Here, we present Fe micro−X-ray absorption near edge structure (μ-XANES) measurements of a suite of impact melt glasses from Lonar crater, India. As an impact into continental flood basalts, Lonar crater is an ideal analog for impacts into basaltic crust on early Earth and Mars. The Fe-μ-XANES technique permits robust characterization of the Fe3+/ΣFe ratio and therefore redox conditions in Lonar glasses. We found a range in Fe3+/ΣFe of 0.21−0.49 among Lonar glasses, including substantial intraclast variations. We conclude that a primary factor driving these variations was pre-impact oxidative weathering of target rocks. The coupling between crustal weathering regime and speciation of gases released from impact melts implies that impact melt outgassing could act as a feedback mechanism to reinforce prevailing surface redox conditions.
期刊介绍:
Published since 1973, Geology features rapid publication of about 23 refereed short (four-page) papers each month. Articles cover all earth-science disciplines and include new investigations and provocative topics. Professional geologists and university-level students in the earth sciences use this widely read journal to keep up with scientific research trends. The online forum section facilitates author-reader dialog. Includes color and occasional large-format illustrations on oversized loose inserts.