Effects of Na2CO3/Na2SO4 on catalytic gasification reactivity and mineral structure of coal gangue

Abstract

In this work, CO₂ catalytic gasification was applied to the utilization of coal gangue (CG). The differences between Na₂CO₃ and Na₂SO₄ catalysts on the effects of the catalytic and activation reaction were evaluated comprehensively. Gasification reactivity and aluminum extraction yield were improved in the presence of both alkali metal salts and increased with increasing temperature at 800–1000 °C. The minerals species in Na₂SO₄ loaded ash (SCA) varied a lot from 800 °C to 850 °C, and the extraction yield can reach the peak (91.39%) at 850 °C. The aluminum ions solution obtained from SCA was purer than that from Na₂CO₃ loaded ash (CCA), this was owing to that SCA has more compact Si–O bond than CCA. What's more, according to the DFT results, Na₂SO₄ had a stronger ability to lengthen the Al–O bond and activate the aluminum in minerals. Besides these, it was found that the sodium in SCA was more favorable for accelerating gasification in theory. This research will contribute to the realization of high-value utilization of CG and Na₂SO₄.