PCB containment using geosynthetics in Canada's Arctic

Abstract

Two funnel-and-gate permeable reactive barriers (PRBs) with settling ponds comprised of a composite liner (geomembrane and geosynthetic clay liners (GCL)) were installed at Resolution Island (BAF-5), Nunavut to contain residual polychlorinated biphenyls (PCBs) moving with the sediment and annual snowmelt. The long-term performance of the geosynthetics used in the PRB funnels is studied for physical integrity and diffusive barrier properties after nine years of operation. Exhumed geomembrane specimens are compared with virgin material by index testing: diffusive resistance to benzene, toluene, ethylbenzene, and xylenes (BTEX) compounds, as well as puncture, burst, and tensile strength. Exhumed GCLs are evaluated concerning hydraulic conductivity, the mass of bentonite per unit area, and swell index. The migration of PCBs through the composite liner system by diffusion is modelled and the diffusive and sorptive properties of the geomembrane (D_g = 1.7 × 10⁻¹⁴ m²/s, S_gf = 160,000) and GCL (D_e = 3.1 × 10⁻¹⁰ m²/s, bentonite plus fibers layer K_d = 15 mL/g, cover geotextile K_d = 12,000 mL/g, and carrier geotextile K_d = 16,000 mL/g) were calculated. Modelling results estimate that the composite liner was successfully containing PCBs. This was confirmed by downgradient monitoring. The challenges of the location and terrain, PRB design, construction, and maintenance are discussed along with recommendations for designing PRBs in other remote and cold region environments.