Polymerization‐induced microphase separation of a polymerization mixture into nanostructured block polymer materials

IF 26 1区化学 Q1 POLYMER SCIENCE

Progress in Polymer Science Pub Date : 2023-10-01 DOI:10.1016/j.progpolymsci.2023.101738

Taeseok Oh , Suchan Cho , Changsu Yoo , Wonjune Yeo , Jinyeong Oh , Myungeun Seo

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引用次数: 1

Abstract

Block polymers comprising covalently joined polymeric segments represent a class of nanostructured, multicomponent polymeric materials. Polymerization-induced microphase separation (PIMS) is an intriguing subset that allows for simultaneous nanostructuring during block polymer synthesis. In contrast to polymerization-induced self-assembly (PISA), useful for the spontaneous formation of block polymer micelles, PIMS is well suited to fabricating monolithic block polymer materials by turning a whole polymerization mixture into a nanostructured solid. With the in situ cross-linking feature, PIMS offers a facile route to nanostructured block polymer thermosets in combination with various polymerization techniques, from emulsion polymerization to 3D printing. This review aims to provide a comprehensive overview and practical guide on PIMS by covering its historical background and mechanistic aspects and also highlighting representative material classes and applicable polymerization techniques.

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聚合诱导聚合混合物微相分离成纳米结构嵌段聚合物材料

嵌段聚合物由共价连接的聚合物段组成，是一类纳米结构的多组分聚合物材料。聚合诱导微相分离(PIMS)是一个有趣的子集，允许在嵌段聚合物合成过程中同时进行纳米结构。与聚合诱导自组装(PISA)相比，PIMS更适合于通过将整个聚合混合物转变为纳米结构固体来制造整体块体聚合物材料。凭借原位交联的特点，PIMS提供了一种简单的途径，可以结合各种聚合技术，从乳液聚合到3D打印，制造纳米结构的嵌段聚合物热固性聚合物。本文综述了PIMS的历史背景和机理，重点介绍了具有代表性的材料类别和适用的聚合技术。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Progress in Polymer Science 化学-高分子科学

CiteScore

48.70

自引率

1.10%

发文量

审稿时长

38 days

期刊介绍： Progress in Polymer Science is a journal that publishes state-of-the-art overview articles in the field of polymer science and engineering. These articles are written by internationally recognized authorities in the discipline, making it a valuable resource for staying up-to-date with the latest developments in this rapidly growing field. The journal serves as a link between original articles, innovations published in patents, and the most current knowledge of technology. It covers a wide range of topics within the traditional fields of polymer science, including chemistry, physics, and engineering involving polymers. Additionally, it explores interdisciplinary developing fields such as functional and specialty polymers, biomaterials, polymers in drug delivery, polymers in electronic applications, composites, conducting polymers, liquid crystalline materials, and the interphases between polymers and ceramics. The journal also highlights new fabrication techniques that are making significant contributions to the field. The subject areas covered by Progress in Polymer Science include biomaterials, materials chemistry, organic chemistry, polymers and plastics, surfaces, coatings and films, and nanotechnology. The journal is indexed and abstracted in various databases, including Materials Science Citation Index, Chemical Abstracts, Engineering Index, Current Contents, FIZ Karlsruhe, Scopus, and INSPEC.