Rational Design of First-Row Transition Metal Complexes as the Catalysts for Oxidation of Arenes: A Homogeneous Approach

IF 11.3 1区化学 Q1 CHEMISTRY, PHYSICAL

ACS Catalysis Pub Date : 2022-08-01 DOI:10.1021/acscatal.2c01928

Anjana Rajeev, Mani Balamurugan and Muniyandi Sankaralingam*,

引用次数: 8

Abstract

Researchers have always been intrigued by one-step selective hydroxylation of aromatic compounds since achieving adequate selectivity toward the target product and avoiding overoxidation are challenging. However, the naturally available oxygenase enzymes efficiently and selectively perform such transformations under normal atmospheric conditions. Inspired by naturally occurring oxygenase enzymes, researchers have undertaken numerous attempts to catalyze the oxidation of arenes using homogeneous and heterogeneous catalysts. In this regard, the first-row transition metal complexes are considered as candidates due to their abundance and redox characteristics. Therefore, this review focuses on catalyst design strategies to improve the efficiency and selectivity of arene oxidation and illustrates the distinctive homogeneous approaches reported in this area by employing first-row transition metal complexes.

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第一排过渡金属配合物作为芳烃氧化催化剂的合理设计:均相方法

研究人员一直对芳香族化合物的一步选择性羟基化很感兴趣，因为实现对目标产物的充分选择性和避免过度氧化是具有挑战性的。然而，天然可用的加氧酶在正常大气条件下有效地和选择性地进行这种转化。受天然存在的加氧酶的启发，研究人员已经进行了许多尝试，用均相和非均相催化剂催化芳烃的氧化。在这方面，由于第一排过渡金属配合物的丰度和氧化还原特性，被认为是候选物。因此，本文将重点介绍提高芳烃氧化效率和选择性的催化剂设计策略，并举例说明在该领域报道的采用第一排过渡金属配合物的独特均相方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ACS Catalysis CHEMISTRY, PHYSICAL-

CiteScore

20.80

自引率

6.20%

发文量

1253

审稿时长

1.5 months

期刊介绍： ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels. The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.