S. M. Orlyk, V. I. Chedryk, S. O. Soloviev, O. D. Vasylyev
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引用次数: 0
Abstract
Modified nickel composites based on stabilized zirconia as prototypes of anode materials of solid oxide fuel cells (SOFC) showed high catalytic activity and stability in the oxidative reforming of alkanes (tri-reforming of methane and steam-(oxygen) reforming of butane). Modification of Ni-10Sc1CeSZ composite with Cu and CeO2 increases its resistance to carbonization, and doping with platinum or palladium (0.1 wt.%) increases the resistance to H2S poisoning. Structured Ni-(CeO2, La2O3)-Al2O3/cordierite catalysts are characterized by high activity and stability in the oxidative reforming of C1-C3 alkanes into syngas and can be effective in an external processor integrated with SOFC. Bench tests of the fuel cell showed the achievement of acceptable electrical characteristics.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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