Direct Injection of Biomineralizing Agents to Restore Injectivity and Wellbore Integrity

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Catherine M. Kirkland, R. Hiebert, R. Hyatt, J. Mccloskey, J. Kirksey, Abby Thane, A. Cunningham, R. Gerlach, L. Spangler, Adrienne J Phillips
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引用次数: 8

Abstract

In this manuscript, we describe the second of two field demonstrations of microbially induced calcium carbonate precipitation (MICP) performed in a failed waterflood injection well in Indiana. In 2012, fracture-related flow pathways developed in the wellbore cement, causing injection water to bypass the oil-bearing formation and enter a high-permeability sandstone thief zone, thereby substantially decreasing injection pressure. In the first field demonstration, our study team characterized the well's mode of failure and successfully applied MICP to decrease flow through the defective cement. However, because the MICP treatment was conducted using a bailer delivery system, the degree of permeability reduction achievable was not adequate to fully restore the historic injection pressure of 1,400 psi at 1 gal/min. For the second field demonstration (reported herein), a direct injection system was developed that substantially increased the injection volume of MICP-promoting fluids. Two strategies were implemented to produce more ureolytic microbes: resuspending concentrated frozen cells immediately before injection and scaling up the bioreactor growth capacity. Multiple pulses of microbes and urea-calcium media were pumped into a string of 1-in.-diameter tubing separated by brine spacers and injected continuously at a flow rate of 3.4 to 1.4 gal/min. During the third day of injection, an injection pressure of 1,384 psi at a flow rate of 1.4 gal/min was achieved, and the experiment was terminated. This study demonstrates that MICP can be successfully used in large-volume applications where the time frame for the delivery of reactants is limited. This finding has significant relevance for commercialization of the MICP biotechnology in the oil and gas industry.
直接注入生物矿化剂以恢复注入能力和井筒完整性
在这份手稿中,我们描述了在印第安纳州一口失败的注水井中进行的微生物诱导碳酸钙沉淀(MICP)的两个现场演示中的第二个。2012年,井筒水泥中形成了与裂缝相关的流动通道,导致注入水绕过含油层,进入高渗透砂岩贼带,从而大幅降低了注入压力。在第一次现场演示中,我们的研究团队描述了油井的失效模式,并成功地应用MICP来减少通过缺陷水泥的流量。然而,由于MICP处理是使用贝勒输送系统进行的,可实现的渗透率降低程度不足以完全恢复1400的历史注入压力 psi,1加仑/分钟。对于第二次现场演示(本文报道),开发了一种直接注射系统,该系统显著增加了MICP促进流体的注射体积。实施了两种策略来产生更多的解脲微生物:在注射前立即重悬浓缩的冷冻细胞和扩大生物反应器的生长能力。微生物和尿素钙介质的多个脉冲被泵送到1英寸的串中-直径的管道,所述管道由盐水间隔器分离并且以3.4至1.4加仑/分钟的流速连续注入。在注射的第三天,注射压力为1384 在1.4gal/min的流速下达到psi,并且终止实验。这项研究表明,MICP可以成功地用于反应物输送时间有限的大容量应用。这一发现对MICP生物技术在石油和天然气行业的商业化具有重要意义。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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