Preface

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Theodore de Bary
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引用次数: 0

Abstract

Of prime concern in this book are combustion systems – confined fields of compressible fluids where exothermic processes of combustion take place. Their purpose is to generate motive power. In their course, exothermic energy* is created by chemical reaction and deposited in the field, both actions carried out concomitantly and referred to popularly as ’heat release.’ Particular examples of such systems are cylinders in internal combustion engines, combustors of gas turbines and rockets, as well as explosions engendering blast waves non-steady flow fields bounded by incident shock fronts that impose on them the constraints of confinement. The process of combustion is carried out, as a rule, at a high rate, the life time of chemically reacting component being of an order of microseconds, while the exothermic reaction of the whole system is accomplished in few milliseconds. For that reason, its execution has been considered so far to be beyond the intervention of interactive controls – a hindrance that, in our age of microelectronics for which a millisecond is a relatively long time, can be eliminated. The technological objective of the book is to pave the way towards this end by bringing forth the dynamic features of combustion systems. Their properties are expressed therefore as those of dynamic objects – entities amenable to management by modern tools of control technology. Sensible properties of combustion systems are displayed in a threedimensional physical space, while their processes are disclosed in a multidimensional thermo-physical phase space, where the states of components of the working substance are identified and the transformations of its constituents are disclosed. The dimension of the latter is equal to the degrees of freedom the number of reaction constituents plus two, as specified by the Gibbs phase rule.
前言
本书主要关注的是燃烧系统——发生燃烧放热过程的可压缩流体的受限区域。它们的目的是产生动力。在它们的过程中,放热能量*是由化学反应产生的,并沉积在现场,这两种作用同时发生,通常被称为“放热”这种系统的具体例子是内燃机中的气缸、燃气轮机和火箭的燃烧器,以及产生冲击波的爆炸——由入射冲击前沿限定的非稳定流场,这些冲击前沿对它们施加了约束。燃烧过程通常以高速率进行,化学反应部件的寿命为微秒级,而整个系统的放热反应在几毫秒内完成。因此,到目前为止,它的执行被认为超出了交互式控制的干预范围——在我们的微电子时代,一毫秒是一个相对较长的时间,这是一个可以消除的障碍。本书的技术目标是通过提出燃烧系统的动态特征为实现这一目标铺平道路。因此,它们的特性被表示为动态对象的特性——可通过现代控制技术工具进行管理的实体。燃烧系统的敏感特性在三维物理空间中显示,而它们的过程在多维热物理相空间中公开,其中识别工作物质成分的状态并公开其成分的转变。后者的尺寸等于自由度,即反应组分的数量加上两个,如吉布斯相规则所规定的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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