Crosslinked Cyclodextrin as Potent Composite For Removal of Wastewater Pollutants

IF 6.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
Nurul Elia Aqila Abu Rahim, Nur Izyan Wan Azelee, Siti Fatimah Zaharah Mohd Fuzi, Nasratun Masngut, Zainul Akmar Zakaria, Azham Zulkharnain, Rosli Md Illias, Nor Hasmaliana Abdul Manas
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Abstract

Purpose of Review

Pollution from wastewater is a perpetual environmental issue worldwide that negatively impacts the ecosystem and human beings. The use of natural-based compounds such as cyclodextrin (CD) to remove pollutants from water and wastewater systems has been reported by various researchers. Nevertheless, its direct use in wastewater treatment is hampered by its water-soluble properties. Beta-cyclodextrin (β-CD) is a cyclic oligosaccharide compound that can effectively trap pollutants from wastewater by the formation of truncated inclusion complex with various molecules. Hence, it is the motivation of this article to review the effectiveness and the recent strategies of crosslinked-β-CD toward remediation of various pollutants from wastewater.

Recent Findings

The crosslinked-β-CD was found as an improvement for native β-CD in the purpose of wastewater pollutant remediation. Strategies in chemical crosslinking include the choice of suitable crosslinkers, the type of support materials, and surface modifications. It was observed that different strategies resulted in various degrees of performance of the composite β-CD adsorbents. The efficiency of adsorption process was influenced by the operational parameters such as pH, contact time, and initial pollutant concentration, whereby it was characterized by the recyclability, adsorption capacity, and mechanical strength. The emergence of nanotechnology has led to a great improvement to the existing composite-β-CD adsorbent by providing a large surface area, where it can be easily functionalized and modified toward the targeted molecules.

Summary

Crosslinking is a versatile method for developing a composite-β-CD adsorbent for pollutant uptake as it employs a simple technique and performs a simple separation process with moderate operational conditions.

Graphical Abstract

The 3D structure of β-cyclodextrin resembles a truncated cone, having characteristics of hydrophilic surface and hydrophobic cavity and capable to trap molecules inside its cavity. The graphical abstract shows the flows of this review paper. The crosslinking strategies, the operational parameters, and the adsorption performance of the composite CD-adsorbents were reviewed and discussed

Abstract Image

交联环糊精作为去除废水污染物的有效复合材料
综述目的废水污染是全球长期存在的环境问题,对生态系统和人类造成了负面影响。许多研究人员都报道过使用环糊精(CD)等天然化合物来去除水和废水系统中的污染物。然而,由于环糊精具有水溶性,因此无法直接用于废水处理。β-环糊精(β-CD)是一种环状寡糖化合物,它能与各种分子形成截短的包合物,从而有效地捕捉废水中的污染物。因此,本文综述了交联-β-CD 在修复废水中各种污染物方面的有效性和最新策略。化学交联的策略包括选择合适的交联剂、支持材料的类型和表面改性。据观察,不同的策略会导致复合 β-CD 吸附剂具有不同程度的性能。吸附过程的效率受 pH 值、接触时间和初始污染物浓度等操作参数的影响,其特点是可回收性、吸附容量和机械强度。纳米技术的出现极大地改进了现有的复合-β-CD 吸附剂,它提供了一个大的表面积,可以很容易地对目标分子进行功能化和改性。图解摘要 β-环糊精的三维结构类似于截顶锥,具有亲水表面和疏水空腔的特点,能够将分子捕集在空腔内。图表摘要显示了本综述论文的流程。本文回顾并讨论了交联策略、操作参数以及 CD- 吸附剂复合材料的吸附性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Current Pollution Reports
Current Pollution Reports Environmental Science-Water Science and Technology
CiteScore
12.10
自引率
1.40%
发文量
31
期刊介绍: Current Pollution Reports provides in-depth review articles contributed by international experts on the most significant developments in the field of environmental pollution.By presenting clear, insightful, balanced reviews that emphasize recently published papers of major importance, the journal elucidates current and emerging approaches to identification, characterization, treatment, management of pollutants and much more.
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