Development of biobased plasticizers with synergistic effects of plasticization, thermal stabilization, and migration resistance: A review

IF 3.8 4区工程技术 Q2 CHEMISTRY, APPLIED

Journal of Vinyl & Additive Technology Pub Date : 2023-09-07 DOI:10.1002/vnl.22048

Yu Han, Yunxuan Weng, Caili Zhang

{"title":"Development of biobased plasticizers with synergistic effects of plasticization, thermal stabilization, and migration resistance: A review","authors":"Yu Han, Yunxuan Weng, Caili Zhang","doi":"10.1002/vnl.22048","DOIUrl":null,"url":null,"abstract":"<div>\n \n \n <section>\n \n <p>Plasticizers are widely used in poly(vinyl chloride) (PVC), polylactic acid (PLA), thermoplastic starch (TPS), and other modified powder materials to enhance the flowability, flexibility, and processability of macromolecules. Because of the reprotoxicity of phthalates in animals and humans, certain phthalates have recently been banned in the United States and Europe. Biobased plasticizers from green biomass–derived renewable resources with low toxicity are expected to be a substitute for phthalates. Among a variety of newly developed biobased monomers, cardanol, and isosorbide are the two most promising materials because of their unique structural features. This review summarizes the research progress of cardanol- and isosorbide-based plasticizers with synergistic effects of plasticization, thermal stabilization, and anti-migration. By summarizing and analyzing the relationship between molecular structure of plasticizer and plasticizing performance, this review can provide theoretical guidance for future research on the design of isosorbide- and cardanol-based plasticizers.</p>\n </section>\n \n <section>\n \n <h3> Highlights</h3>\n \n <div>\n <ul>\n \n <li>Biobased plasticizers with low toxicity are expected to replace certain phthalates.</li>\n \n <li>The plasticizing effect of single biobased plasticizer is not good.</li>\n \n <li>Biobased plasticizer with synergistic effects is required.</li>\n \n <li>There exists the trade-off effect between the molecular weight and the compatibility.</li>\n \n <li>Epoxidized isosorbide ester can be used as a heat stabilizer.</li>\n </ul>\n </div>\n </section>\n </div>","PeriodicalId":17662,"journal":{"name":"Journal of Vinyl & Additive Technology","volume":"30 1","pages":"26-43"},"PeriodicalIF":3.8000,"publicationDate":"2023-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Vinyl & Additive Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/vnl.22048","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}

引用次数: 0

Abstract

Plasticizers are widely used in poly(vinyl chloride) (PVC), polylactic acid (PLA), thermoplastic starch (TPS), and other modified powder materials to enhance the flowability, flexibility, and processability of macromolecules. Because of the reprotoxicity of phthalates in animals and humans, certain phthalates have recently been banned in the United States and Europe. Biobased plasticizers from green biomass–derived renewable resources with low toxicity are expected to be a substitute for phthalates. Among a variety of newly developed biobased monomers, cardanol, and isosorbide are the two most promising materials because of their unique structural features. This review summarizes the research progress of cardanol- and isosorbide-based plasticizers with synergistic effects of plasticization, thermal stabilization, and anti-migration. By summarizing and analyzing the relationship between molecular structure of plasticizer and plasticizing performance, this review can provide theoretical guidance for future research on the design of isosorbide- and cardanol-based plasticizers.

Highlights

Biobased plasticizers with low toxicity are expected to replace certain phthalates.
The plasticizing effect of single biobased plasticizer is not good.
Biobased plasticizer with synergistic effects is required.
There exists the trade-off effect between the molecular weight and the compatibility.
Epoxidized isosorbide ester can be used as a heat stabilizer.

Abstract Image

查看原文本刊更多论文

具有增塑剂、热稳定剂和抗迁移剂协同作用的生物基增塑剂的研究进展

增塑剂广泛应用于聚氯乙烯（PVC）、聚乳酸（PLA）、热塑性淀粉（TPS）和其他改性粉末材料中，以增强大分子的流动性、柔韧性和可加工性。由于邻苯二甲酸酯对动物和人类具有再毒性，某些邻苯二甲酸酯最近在美国和欧洲被禁止使用。来自绿色生物质可再生资源的低毒生物增塑剂有望取代邻苯二甲酸酯。在各种新开发的生物基单体中，腰果醇和异山梨醇因其独特的结构特征而成为最有前途的两种材料。本文综述了腰果醇和异山梨醇基增塑剂的研究进展，这些增塑剂具有增塑、热稳定性和抗迁移的协同作用。通过总结和分析增塑剂的分子结构与增塑性能之间的关系，本综述可为今后异山梨醇和腰果醇基增塑剂设计研究提供理论指导。低毒的生物基增塑剂有望取代某些邻苯二甲酸酯。单一生物基增塑剂的增塑效果不好。需要具有协同作用的生物基增塑剂。分子量和相容性之间存在权衡效应。环氧化异山梨醇酯可用作热稳定剂。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Vinyl & Additive Technology 工程技术-材料科学：纺织

CiteScore

5.40

自引率

14.80%

发文量

审稿时长

>12 weeks

期刊介绍： Journal of Vinyl and Additive Technology is a peer-reviewed technical publication for new work in the fields of polymer modifiers and additives, vinyl polymers and selected review papers. Over half of all papers in JVAT are based on technology of additives and modifiers for all classes of polymers: thermoset polymers and both condensation and addition thermoplastics. Papers on vinyl technology include PVC additives.