Solid-state mechanochemistry advancing two dimensional materials for lithium-ion storage applications: A mini review

IF 9.9 2区材料科学 Q1 Engineering

Nano Materials Science Pub Date : 2023-06-01 DOI:10.1016/j.nanoms.2022.03.005

Xingang Liu , Wenbin Kang , Xi Li, Li Zeng, Yijun Li, Qi Wang, Chuhong Zhang

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引用次数: 10

Abstract

The vigorous development of two-dimensional (2D) materials brings about numerous opportunities for lithium-ion batteries (LIBs) due to their unique 2D layered structure, large specific surface area, outstanding mechanical and flexibility properties, etc. Modern technologies for production of 2D materials include but are not limited to mechanochemical (solid-state/liquid-phase) exfoliation, the solvothermal method and chemical vapor deposition. In this review, strategies leading to the production of 2D materials via solid-state mechanochemistry featuring traditional high energy ball-milling and Sichuan University patented pan-milling are highlighted. The mechanism involving exfoliation, edge selective carbon radical generation of the 2D materials is delineated and this is followed by detailed discussion on representative mechanochemical techniques for tailored and improved lithium-ion storage performance. In the light of the advantages of the solid-state mechanochemical method, there is great promise for the commercialization of 2D materials for the next-generation high performance LIBs.

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固态机械化学促进锂离子存储应用的二维材料：综述

二维（2D）材料的蓬勃发展为锂离子电池（LIBs）带来了许多机会，因为它们具有独特的二维层状结构、大的比表面积、突出的机械和柔性特性等。生产2D材料的现代技术包括但不限于机械化学（固态/液相）剥离，溶剂热法和化学气相沉积。在这篇综述中，重点介绍了通过固态机械化学生产2D材料的策略，包括传统的高能球磨和四川大学获得专利的pan铣削。描述了2D材料的剥离、边缘选择性碳自由基产生的机制，随后详细讨论了用于定制和改进锂离子存储性能的代表性机械化学技术。鉴于固态机械化学方法的优势，用于下一代高性能LIBs的2D材料的商业化前景广阔。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Nano Materials Science Engineering-Mechanics of Materials

CiteScore

20.90

自引率

3.00%

发文量

294

审稿时长

9 weeks

期刊介绍： Nano Materials Science (NMS) is an international and interdisciplinary, open access, scholarly journal. NMS publishes peer-reviewed original articles and reviews on nanoscale material science and nanometer devices, with topics encompassing preparation and processing; high-throughput characterization; material performance evaluation and application of material characteristics such as the microstructure and properties of one-dimensional, two-dimensional, and three-dimensional nanostructured and nanofunctional materials; design, preparation, and processing techniques; and performance evaluation technology and nanometer device applications.