Effect of an External Magnetic Field on the Hydrogen Reduction of Magnetite Nanoparticles in a Polymer Matrix

IF 2.5 4区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
P. Chernavskii, S. Ozkan, G. Karpacheva, G. Pankina, N. Perov
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引用次数: 0

Abstract

A hybrid electromagnetic nanomaterial, which is a matrix based on a conjugated polymer of poly-3-amine-7-methylamine-2-methylphenazine with dispersed magnetite nanoparticles immobilized on multi-walled carbon nanotubes, has been synthesized. In situ magnetometry was used to study the kinetics of the hydrogen reduction of Fe3O4 immobilized in the structure of a ternary nanocomposite in magnetic fields of different intensities. An increase in the magnetite reduction reaction rate with the formation of metallic iron nanoparticles at T=420∘C and at a magnetic field strength in the range of 60–3000 Oe was observed. The dependence of the degree of conversion of Fe3O4 on the magnetic field strength was established.
外磁场对聚合物基体中磁性纳米粒子氢还原的影响
合成了一种混合电磁纳米材料,该材料是以聚-3-胺-7-甲胺-2-甲基吩嗪与固定在多壁碳纳米管上的分散磁铁矿纳米颗粒的共轭聚合物为基体。采用原位磁法研究了固定在三元纳米复合材料结构中的Fe3O4在不同强度磁场中的氢还原动力学。在T=420∘C和60–3000 Oe的磁场强度范围内,随着金属铁纳米颗粒的形成,磁铁矿还原反应速率增加。建立了Fe3O4的转化率与磁场强度的关系。
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来源期刊
Magnetochemistry
Magnetochemistry Chemistry-Chemistry (miscellaneous)
CiteScore
3.90
自引率
11.10%
发文量
145
审稿时长
11 weeks
期刊介绍: Magnetochemistry (ISSN 2312-7481) is a unique international, scientific open access journal on molecular magnetism, the relationship between chemical structure and magnetism and magnetic materials. Magnetochemistry publishes research articles, short communications and reviews. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.
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