P. Chernavskii, S. Ozkan, G. Karpacheva, G. Pankina, N. Perov
{"title":"Effect of an External Magnetic Field on the Hydrogen Reduction of Magnetite Nanoparticles in a Polymer Matrix","authors":"P. Chernavskii, S. Ozkan, G. Karpacheva, G. Pankina, N. Perov","doi":"10.3390/magnetochemistry9050123","DOIUrl":null,"url":null,"abstract":"A hybrid electromagnetic nanomaterial, which is a matrix based on a conjugated polymer of poly-3-amine-7-methylamine-2-methylphenazine with dispersed magnetite nanoparticles immobilized on multi-walled carbon nanotubes, has been synthesized. In situ magnetometry was used to study the kinetics of the hydrogen reduction of Fe3O4 immobilized in the structure of a ternary nanocomposite in magnetic fields of different intensities. An increase in the magnetite reduction reaction rate with the formation of metallic iron nanoparticles at T=420∘C and at a magnetic field strength in the range of 60–3000 Oe was observed. The dependence of the degree of conversion of Fe3O4 on the magnetic field strength was established.","PeriodicalId":18194,"journal":{"name":"Magnetochemistry","volume":" ","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2023-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Magnetochemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.3390/magnetochemistry9050123","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
A hybrid electromagnetic nanomaterial, which is a matrix based on a conjugated polymer of poly-3-amine-7-methylamine-2-methylphenazine with dispersed magnetite nanoparticles immobilized on multi-walled carbon nanotubes, has been synthesized. In situ magnetometry was used to study the kinetics of the hydrogen reduction of Fe3O4 immobilized in the structure of a ternary nanocomposite in magnetic fields of different intensities. An increase in the magnetite reduction reaction rate with the formation of metallic iron nanoparticles at T=420∘C and at a magnetic field strength in the range of 60–3000 Oe was observed. The dependence of the degree of conversion of Fe3O4 on the magnetic field strength was established.
期刊介绍:
Magnetochemistry (ISSN 2312-7481) is a unique international, scientific open access journal on molecular magnetism, the relationship between chemical structure and magnetism and magnetic materials. Magnetochemistry publishes research articles, short communications and reviews. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.