Crust occurrence on a Galatian rock-cut dwelling in central Anatolia, Turkey

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Nizamettin Kazancı, Aysen Özgüneylioğlu, Salim M. Öncel, Mehmet Korhan Erturaç, Eren Şahiner
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Abstract

Mahkemağcin Underground City (MUC) is a four-floored rock-cut dwelling complex carved into ignimbrite tuffs of the Early-Middle Miocene age in central Anatolia. The whole interior of the complex is covered by a 1–5 cm thick alteration crust that is not detected in any cave or outcrop in the region. This crust is investigated using microscopy, scanning electron microscopy, X-ray diffraction and X-ray fluorescence analyses, and the results are discussed from the geomechanical point of view. The colour of the outer surface of the crust is black, which turns red inside and grades into pale yellow above the white parent rock. The compaction and solidity of the crust are relatively high, as much as double that of the parent rock. The crust seems to have prevented and/or significantly decreased the erosion of the surfaces of the room walls. Mineralogical and chemical analyses together with experimental studies on selected samples suggest that such a crust could have formed because of thermal alteration at high temperatures ca. 600–950°C. On examination of the heated samples, the main geochemical changes within heated rocks were (i) an increase in silica concentration by ca. 2%–3% and (ii) the disappearance of zeolites and sericites. Thermoluminescence dating of the crust revealed thermal resetting of quartz crystals within the ignimbrite tuff at 243 ± 260 CE. All the analytical methods applied to the site indicate that the crust was obtained intentionally, possibly by burning woods indoors, aiming to harden the wall surfaces, mainly by Galatian people of the early Medieval time.

土耳其安纳托利亚中部加拉太岩切住宅上的地壳
Mahkemağcin地下城(MUC)是位于安纳托利亚中部中新世早期的褐煤凝灰岩中雕刻的四层岩石切割住宅综合体。杂岩体的整个内部覆盖着1-5厘米厚的蚀变地壳,这在该地区的任何洞穴或露头中都没有发现。利用显微镜、扫描电镜、x射线衍射和x射线荧光分析对该地壳进行了研究,并从地质力学的角度对结果进行了讨论。地壳的外表面是黑色的,内部是红色的,在白色的母岩上方逐渐变成淡黄色。地壳的压实度和坚固度相对较高,是母岩的两倍。地壳似乎已经阻止和/或显著减少了房间墙壁表面的侵蚀。矿物学和化学分析以及对选定样品的实验研究表明,这种地壳可能是由于高温(约600-950°C)的热蚀变而形成的。加热后岩石的地球化学变化主要表现在:(1)二氧化硅浓度增加约2% ~ 3%,(2)沸石和绢云母消失。地壳的热释光测年显示,在243±260 CE,菱灰岩凝灰岩内部的石英晶体发生了热重置。所有用于该遗址的分析方法都表明,地壳是故意获得的,可能是在室内燃烧木材,目的是使墙壁表面变硬,主要是中世纪早期的加拉太人。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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