The microwave spectra and molecular structures of (Z)-1-chloro-3,3,3-trifluoropropene and its gas-phase heterodimer with the argon atom

IF 1.4 4区 物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
Helen O. Leung, Mark D. Marshall, Seohyun Hong, Laboni Hoque
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引用次数: 1

Abstract

The microwave spectra of (Z)-1-chloro-3,3,3-trifluoropropene and its gas-phase heterodimer with the argon atom in the 5.6 to 18.1 GHz frequency range are first observed and assigned using broadband, chirped pulse, Fourier transform microwave (FTMW) spectroscopy. Subsequent analysis of higher-resolution spectra obtained between 5 and 21 GHz with a narrowband, Balle-Flygare FTMW instrument provides spectroscopic constants, including nuclear quadrupole coupling constants, for five isotopologues of the propene molecule and two isotopologues of the complex with argon. Structural parameters obtained from these spectra show the existence of an intramolecular hydrogen bond between one of the fluorine atoms of the trifluoromethyl group and the hydrogen atom on the adjacent carbon atom. No evidence is seen for internal rotation of the trifluoromethyl group. The location of the argon atom in the heterodimer is consistent with the expectation that it will be positioned so to interact with the greatest number of heavy atoms, and in particular, the polarizable chlorine atom.

Abstract Image

(Z)-1-氯-3,3,3-三氟丙烯及其氩原子气相杂二聚体的微波光谱和分子结构
利用宽带啁啾脉冲傅立叶变换微波(FTMW)光谱,首次观测了(Z)-1-氯-3,3,3-三氟丙烯及其气相异二聚体在5.6 ~ 18.1 GHz频率范围内的微波光谱。随后,对5 ~ 21 GHz窄带高分辨率光谱进行分析,Balle-Flygare FTMW仪器提供了五个丙烯分子的同位素物和两个与氩配合物的同位素物的光谱常数,包括核四极耦合常数。从这些光谱得到的结构参数表明,在三氟甲基的一个氟原子和相邻碳原子上的氢原子之间存在分子内氢键。没有证据表明三氟甲基有内旋。氩原子在异二聚体中的位置与预期一致,即它的位置是为了与最多数量的重原子,特别是可极化的氯原子相互作用。
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来源期刊
CiteScore
2.70
自引率
21.40%
发文量
94
审稿时长
29 days
期刊介绍: The Journal of Molecular Spectroscopy presents experimental and theoretical articles on all subjects relevant to molecular spectroscopy and its modern applications. An international medium for the publication of some of the most significant research in the field, the Journal of Molecular Spectroscopy is an invaluable resource for astrophysicists, chemists, physicists, engineers, and others involved in molecular spectroscopy research and practice.
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