Diagnosing the environmental impacts of typical fatliquors in leather manufacture from life cycle assessment perspective

Yue Yu, Qingyong Sun, Yunhang Zeng, Yirui Lin, Ya-nan Wang, Bi Shi
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引用次数: 5

Abstract

The environmental impacts of typical fatliquors were diagnosed by the life cycle assessment of industrial production and use (post-tanning) processes. Life cycle impact assessment and sensitivity analysis showed that fatliquor and fatliquoring operation were the major contributors to the environmental impacts of post-tanning because a large amount of fatliquors was consumed during fatliquoring operation. The environmental impacts of fatliquors decreased in the following order: chlorinated paraffin (CP) > sulfonated rape oil (SNR) > sulfated rape oil (SR) > phosphated rape oil (PR) > oxidized–sulfited rape oil (OSR). Sulfuric acid, fuming sulfuric acid, and chlorine used for fatliquor modification gave the main contribution to most impact categories for SR, SNR, and CP production, whereas rape oil contributed the most for PR and OSR production. OSR use process reduced the primary energy demand, abiotic depletion potential, and global warming potential by 38.5%, 56.0%, and 48.5%, respectively, compared with CP use process. These results suggested that biomass-derived fatliquors, especially oxidized–sulfited and phosphate modified fatiliquors, helped reduce the environmental burdens in leather manufacturing.

Graphical Abstract

从生命周期评价的角度分析皮革生产中典型加脂剂对环境的影响
通过对工业生产和使用(鞣制后)过程的生命周期评价,对典型加脂剂的环境影响进行了诊断。生命周期影响评价和敏感性分析表明,加脂剂和加脂操作是鞣制后环境影响的主要因素,因为加脂操作消耗了大量的加脂剂。加脂剂对环境的影响从大到小依次为:氯化石蜡(CP) >磺化菜籽油(SNR) >磺化菜籽油(SR) >磷酸菜籽油(PR) >氧化亚硫酸菜籽油(OSR)。对SR、SNR和CP产量影响最大的是硫酸、发烟硫酸和加脂剂改性用氯,而对PR和OSR产量影响最大的是菜籽油。OSR利用过程与CP利用过程相比,一次能源需求、非生物耗竭潜力和全球变暖潜力分别降低了38.5%、56.0%和48.5%。这些结果表明,生物质衍生的脂质油,特别是氧化亚硫酸盐和磷酸盐改性脂质油,有助于减轻皮革制造业的环境负担。图形抽象
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来源期刊
Journal of Leather Science and Engineering
Journal of Leather Science and Engineering 工程技术-材料科学:综合
CiteScore
12.80
自引率
0.00%
发文量
29
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