Two 2D Zn(II) coordination polymers assembled from thiophene dicarboxylate and flexible N-(4-pyridylmethyl)imidazole derivatives: syntheses, crystal structures, and photoluminescent properties
{"title":"Two 2D Zn(II) coordination polymers assembled from thiophene dicarboxylate and flexible N-(4-pyridylmethyl)imidazole derivatives: syntheses, crystal structures, and photoluminescent properties","authors":"Li-Ping Xue , Qing Wang","doi":"10.1080/17415993.2022.2101890","DOIUrl":null,"url":null,"abstract":"<div><p>Two 2D Zn(II) coordination polymers, formulated as [Zn(<em>μ</em><sub>2</sub>-tdc)(<em>μ</em>-pmid)] (<strong>1</strong>), {[Zn(<em>μ</em><sub>2</sub>-tdc)(<em>μ</em>-pmmid)<sub>2</sub>·4H<sub>2</sub>O]}<sub>n</sub> (<strong>2</strong>) (H<sub>2</sub>tdc = 2,5-thiophenedicarboxylic acid, pmid = 1-(4-pyridylmethyl)imidazole; pmmid = 1-(4-pyridylmethyl)-2-methylimidazole) have been synthesized by reactions of Zn(OAc)<sub>2</sub>·2H<sub>2</sub>O and H<sub>2</sub>tdc with flexibleN-(4-pyridylmethyl)imidazole derivatives under the mild reaction conditions and characterized by single-crystal X-ray diffraction and other physicochemical methods. Structure determination demonstrates compound <strong>1</strong> displays a 2-fold 2D → 2D parallel interpenetrating structure, while compound 2 shows a 2D non-interpenetrating network. These results reveal that the substitute group in such N-(4-pyridylmethyl)imidazole derivatives might be the main factor resulting in these interpenetrating/ non-interpenetrating structures.Furthermore, compounds <strong>1</strong> and <strong>2</strong> show different thermal stabilities and strong solid-state luminescence emissions.</p></div>","PeriodicalId":17081,"journal":{"name":"Journal of Sulfur Chemistry","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2023-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Sulfur Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1741599323000478","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1
Abstract
Two 2D Zn(II) coordination polymers, formulated as [Zn(μ2-tdc)(μ-pmid)] (1), {[Zn(μ2-tdc)(μ-pmmid)2·4H2O]}n (2) (H2tdc = 2,5-thiophenedicarboxylic acid, pmid = 1-(4-pyridylmethyl)imidazole; pmmid = 1-(4-pyridylmethyl)-2-methylimidazole) have been synthesized by reactions of Zn(OAc)2·2H2O and H2tdc with flexibleN-(4-pyridylmethyl)imidazole derivatives under the mild reaction conditions and characterized by single-crystal X-ray diffraction and other physicochemical methods. Structure determination demonstrates compound 1 displays a 2-fold 2D → 2D parallel interpenetrating structure, while compound 2 shows a 2D non-interpenetrating network. These results reveal that the substitute group in such N-(4-pyridylmethyl)imidazole derivatives might be the main factor resulting in these interpenetrating/ non-interpenetrating structures.Furthermore, compounds 1 and 2 show different thermal stabilities and strong solid-state luminescence emissions.
期刊介绍:
The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science.
Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.