Synthesis of amphiphilic Janus gold nanoparticles stabilized with triphenylphosphine and D-penicillamine by ligand exchange at toluene/water emulsion interface

Abstract

Ligand exchange was triggered at toluene/water emulsion interface between homogeneous gold nanoparticles (Au NPs) with triphenylphosphine (PPh₃) and D-penicillamine (D-PA), resulted in amphiphilic Janus Au NPs with both phosphine and thiolate ligands. TEM and XRD analyses indicate that the product is composed of Au nanocrystals in an average diameter of about 3.7?nm. XPS, FTIR, Raman, and ¹H NMR analyses demonstrate that the Au NPs are protected with hydrophilic D-PA molecules and lipophilic PPh₃ ligands in a molecular ratio of ca. 1.8. The NOESY analysis and contact angle measurement further suggest that the D-PA and PPh₃ molecules are spontaneously separated to form compartmentalized hydrophilic and lipophilic regions on the individual Au NPs, which exhibit good catalytic performance and recyclability on the reduction of 4-nitrophenol. The results demonstrate that amphiphilic Janus Au NPs can be synthesized by partly exchange of PPh₃ with D-PA at toluene/water emulsion interface and are potentially applicable for other phosphine/thiolate pairs to modify Au NPs.