Anwar H. Khan, Kieran Tait, Richard G. Derwent, Steve Roome, Asan Bacak, Steve Bullock, Mark H. Lowenberg, Dudley E. Shallcross
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引用次数: 0
Abstract
Application of formation flights to civil aviation is gaining interest, primarily due to the fuel burn reduction achieved by flying through another aircraft's wake. However, it is emerging that there are additional, less-recognized climate benefits via reduction in ozone and contrail warming through this concept. The NOx threshold level is defined as when the loss rate for OH by reaction with NO2 is equal to the loss rates for OH with CO and CH4, beyond which level, ozone formation will decrease. In this study, The NOx threshold level was calculated at different altitudes and found that at cruise altitude (∼10 km), the amount of NO2 required for parity in OH loss with loss due to reaction with CO and CH4 is around 2 ppb. The spatial and temporal NOx threshold levels were estimated by STOCHEM-Common Representative Intermediate (CRI) global chemical transport model and In-service Aircraft for Global Observing System (IAGOS) measurement data and found that northern midlatitudes of the atmosphere are the most favorable region existing with the smallest NOx thresholds (0.5 ppb) needed before reduction in ozone formation is likely to occur at cruise altitude of aircraft. Incorporating the major air traffic corridors into the coarse spatial resolution of the chemical transport model overestimated the NOx compensation point, that is, increased photochemical ozone production. Thus, a simple one-dimensional (1D) aircraft plume dispersion model was developed with higher spatial and temporal resolution for considering aircraft plumes and its chemistry more accurately. The model run shows that the impact of formation flying aircraft emissions on spatially averaged ozone could be halved if the aircraft could maintain separations inside 4 km relative to well separated flights of 10 km or more.
编队飞行在民用航空中的应用正受到越来越多的关注,主要是由于通过另一架飞机的尾流飞行可以减少燃油消耗。然而,通过这一概念,通过减少臭氧和尾迹变暖,出现了额外的、不太为人所知的气候效益。NOx的阈值水平定义为当OH与NO2反应的损失率等于OH与CO和CH4的损失率时,超过该水平,臭氧的形成就会减少。在本研究中,计算了不同高度的NOx阈值水平,发现在巡航高度(~ 10公里),由于与CO和CH4反应而导致的OH损失的对等所需的NO2量约为2 ppb。利用STOCHEM-Common Representative Intermediate (CRI)全球化学输运模式和IAGOS (in -service Aircraft for global Observing System, IAGOS)测量数据估算了NOx的时空阈值水平,发现大气中纬度北部是目前存在的最有利区域,在飞机巡航高度可能发生臭氧形成减少之前,NOx阈值最小(0.5 ppb)。将主要空中交通走廊纳入化学运输模型的粗空间分辨率中,高估了NOx补偿点,即光化学臭氧产量的增加。因此,建立了一个简单的一维(1D)飞机羽流弥散模型,该模型具有更高的时空分辨率,可以更准确地考虑飞机羽流及其化学成分。模型运行表明,如果编队飞行的飞机能够保持4公里的间隔,相对于10公里或更长间隔的飞行,编队飞行的飞机排放对空间平均臭氧的影响可以减少一半。
期刊介绍:
As the leading archival journal devoted exclusively to chemical kinetics, the International Journal of Chemical Kinetics publishes original research in gas phase, condensed phase, and polymer reaction kinetics, as well as biochemical and surface kinetics. The Journal seeks to be the primary archive for careful experimental measurements of reaction kinetics, in both simple and complex systems. The Journal also presents new developments in applied theoretical kinetics and publishes large kinetic models, and the algorithms and estimates used in these models. These include methods for handling the large reaction networks important in biochemistry, catalysis, and free radical chemistry. In addition, the Journal explores such topics as the quantitative relationships between molecular structure and chemical reactivity, organic/inorganic chemistry and reaction mechanisms, and the reactive chemistry at interfaces.