A multiphase model for exploring electrochemical Marangoni flow

IF 4.7 3区 工程技术 Q2 ELECTROCHEMISTRY
E. Karimi-Sibaki , A. Vakhrushev , A. Kadylnykova , M. Wu , A. Ludwig , J. Bohacek , A. Kharicha
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引用次数: 0

Abstract

A multiphase numerical model based on the volume of fluid (VOF) method is proposed to simulate the transient, electrochemically-generated Marangoni flow in a system comprising a NaOH electrolyte and a eutectic gallium–indium (EGaIn) metal droplet. The model incorporates appropriate equations to accurately represent the transport phenomena, including flow, electric potential, and electric current density, within the entire system. The model includes the transient variation in the interfacial tension as a function of electric current density at the interface, leading to the generation of Marangoni flow and enabling the tracking of droplet shape evolution. Notably, the model successfully captures the elongation of the droplet towards the cathode, which is validated through comparison with available experimental data.

Abstract Image

用于探测电化学Marangoni流的多相模型
提出了一种基于流体体积法(VOF)的多相数值模型,用于模拟由NaOH电解质和共晶镓铟(EGaIn)金属液滴组成的系统中电化学产生的瞬态Marangoni流动。该模型包含了适当的方程,以准确地表示整个系统内的输运现象,包括流量、电势和电流密度。该模型将界面张力的瞬态变化作为界面电流密度的函数,导致马兰戈尼流的产生,并实现液滴形状演变的跟踪。值得注意的是,该模型成功地捕获了液滴向阴极的延伸率,并通过与现有实验数据的比较验证了这一点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Electrochemistry Communications
Electrochemistry Communications 工程技术-电化学
CiteScore
8.50
自引率
3.70%
发文量
160
审稿时长
1.2 months
期刊介绍: Electrochemistry Communications is an open access journal providing fast dissemination of short communications, full communications and mini reviews covering the whole field of electrochemistry which merit urgent publication. Short communications are limited to a maximum of 20,000 characters (including spaces) while full communications and mini reviews are limited to 25,000 characters (including spaces). Supplementary information is permitted for full communications and mini reviews but not for short communications. We aim to be the fastest journal in electrochemistry for these types of papers.
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