{"title":"STUDY OF PHASE FORMATION IN FE2O3-ND2O3→NDFEO3/FE2O3 NANOCOMPOSITES AS A RESULT OF THERMAL ANNEALING","authors":"K. Egizbek, K. Kadyrzhanov","doi":"10.26577/rcph.2021.v78.i3.05","DOIUrl":null,"url":null,"abstract":"The aim of this work is systematic study of the thermal annealing effect on the preparation of nanostructured composites NdFeO3/Fe2O3 with a spinel type structure. The interest in these nanocomposites is due to the enormous potential of their application as a basis for magnetic devices, catalysts, and magnetic carriers for targeted drug delivery. As a synthesis method, twostage synthesis was used, which includes mechanochemical grinding of nanopowders Fe2O3 and Nd2O3 in a planetary mill, followed by thermal annealing of the resulting mixture in a wide temperature range: 6001000°C. During the studies carried out, it was found that in the initial state the obtained nanocomposites are a mixture of a solid solution of interstitial and substitutional Fe2O3 and Nd2O3. At an annealing temperature of 600°C, the onset of the formation of the NdFeO3 phase is observed, which at a temperature of 1000°C is fully formed and dominates in the composite structure (content more than 85%). It was also found that during thermal sintering, the processes of phase transformations of the Fe2O3Nd2O3→NdFeO3/Fe2O3 type are accompanied by an increase in the particle size by a factor of 1.52","PeriodicalId":29678,"journal":{"name":"Recent Contributions to Physics","volume":null,"pages":null},"PeriodicalIF":0.2000,"publicationDate":"2021-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Recent Contributions to Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.26577/rcph.2021.v78.i3.05","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The aim of this work is systematic study of the thermal annealing effect on the preparation of nanostructured composites NdFeO3/Fe2O3 with a spinel type structure. The interest in these nanocomposites is due to the enormous potential of their application as a basis for magnetic devices, catalysts, and magnetic carriers for targeted drug delivery. As a synthesis method, twostage synthesis was used, which includes mechanochemical grinding of nanopowders Fe2O3 and Nd2O3 in a planetary mill, followed by thermal annealing of the resulting mixture in a wide temperature range: 6001000°C. During the studies carried out, it was found that in the initial state the obtained nanocomposites are a mixture of a solid solution of interstitial and substitutional Fe2O3 and Nd2O3. At an annealing temperature of 600°C, the onset of the formation of the NdFeO3 phase is observed, which at a temperature of 1000°C is fully formed and dominates in the composite structure (content more than 85%). It was also found that during thermal sintering, the processes of phase transformations of the Fe2O3Nd2O3→NdFeO3/Fe2O3 type are accompanied by an increase in the particle size by a factor of 1.52