Size-complementary effects of PEG diamine 1,1’-disubstituted ferrocene on incorporations of β- and γ-cyclodextrins and syntheses of poly(pseudo)rotaxanes with lower coverages therefrom

IF 2.3 4区化学 Q2 Agricultural and Biological Sciences

Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2021-10-09 DOI:10.1007/s10847-021-01104-3

Rong-hao Song, Ming Gao, Xue Geng, Lin Ye, Ai-ying Zhang, Zeng-guo Feng

引用次数: 2

Abstract

Poly(ethylene glycol) diamine 1,1’-disubstituted ferrocene was utilized as a size-com-plementary site to synthesize lower coverage pseudopolyrotaxanes (pPRs) from self-assemblies with β- and γ-cyclodextrins (CDs). After end-capping β-CD pPRs using N-(triphenylmethyl)glycine (Trt-Gly-OH), an exact β-CD [3]polyrotaxane (PR) was created. However, an unexpected γ-CD [2]PR and a predictive chain folded stranded γ-CD pPR were identified from end-capped γ-CD pPRs.

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聚乙二醇二胺1,1′-二取代二茂铁对β-和γ-环糊精结合及低覆盖率聚(伪)轮烷合成的尺寸互补效应

以聚乙二醇二胺1,1′-二取代二茂铁为尺寸互补位点，与β-和γ-环糊精(CDs)自组装合成了低覆盖率的伪聚轮烷(pPRs)。用N-(三苯基甲基)甘氨酸(Trt-Gly-OH)对β-CD pPRs进行端盖后，生成了精确的β-CD[3]聚轮烷(PR)。然而，从末端盖帽的γ-CD pPR中鉴定出了意想不到的γ-CD [2]PR和预测链折叠链γ-CD pPR。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Inclusion Phenomena and Macrocyclic Chemistry 化学-化学综合

CiteScore

3.30

自引率

8.70%

发文量

审稿时长

3-8 weeks

期刊介绍： The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.