The Refining Capability of Palm Shell Activated Carbon for Waste Cooking Oil

M. Ulfah, Chrisatya Nugraha Tamanampo, S. Sunardi
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Abstract

The high level of consumption of cooking oil will have an impact on increasing the waste of cooking oil produced. Using the waste of cooking oil needed purification, including through the adsorption process using activated carbon. This research aimed to study the ability of palm kernel shell activated carbon (PKSAC-AC260) compared to standard activated carbon (DAC or Decolorized Activated Charcoal by Sigma-Aldrich) in refining waste cooking oil at various concentrations of activated carbon. The results showed that the type of activated carbon influenced color, free fatty acid content, peroxide value, and saponification value of purified waste cooking oil, but had no effect on water content, saponification value and iodine value. Activated carbon between PKSAC-AC260 and DAC with a concentration of 2.5% was able to improve the quality of the best waste cooking oil. Purification of used cooking oil using PKSAC-AC260 and DAC was able to increase the color brightness of waste cooking oil (∆E) by 5.44 and 4.53, reduce the free fatty acid content of waste cooking oil from 1.47% to 0.79% and 0.61%, reduce the peroxide value of waste cooking oil from 163.47 meq/kg to 116.40 meq/kg and 98.82 meq/kg, and increase the saponification value of waste cooking oil from 155.22 mg/g to 180.48 mg/g and 184.48 mg/g, respectively. The ability of PKSAC-AC260 to purify waste cooking oil is lower than that of DAC. The quality of processed oil from waste cooking oil does not meet the quality standards of cooking oil based on SNI 3741: 2013.
棕榈壳活性炭对废食用油的精炼性能研究
食用油的高消费量将对产生的食用油浪费增加产生影响。利用废油需要净化,包括通过活性炭吸附过程。本研究旨在研究棕榈仁壳活性炭(PKSAC-AC260)与标准活性炭(DAC或Sigma-Aldrich脱色活性炭)在不同浓度活性炭下精炼废食用油的能力。结果表明,活性炭的种类对纯化后废食用油的色泽、游离脂肪酸含量、过氧化值和皂化值有影响,但对其含水量、皂化值和碘值无影响。在PKSAC-AC260和DAC之间添加浓度为2.5%的活性炭,对食用油质量的改善效果最好。采用PKSAC-AC260和DAC对废食用油进行净化后,废食用油的色度(∆E)分别提高5.44和4.53,废食用油的游离脂肪酸含量从1.47%降低到0.79%和0.61%,废食用油的过氧化值从163.47 meq/kg降低到116.40 meq/kg和98.82 meq/kg,废食用油的皂化值从155.22 mg/g分别提高到180.48 mg/g和184.48 mg/g。PKSAC-AC260对废食用油的净化能力低于DAC。废食用油加工成品油的质量不符合SNI 3741: 2013食用油质量标准。
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