A comprehensive study of the batch-to-melt conversion process of a high-boron alkaline earth aluminosilicate glass

IF 2.1 3区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Hong Li, Manuela Reben, Jason Dobyne, Qingwei Wang, Xiaoyun Liu
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引用次数: 1

Abstract

A comprehensive study of the batch-to-melt (BtM) conversion process was carried out on a single high-boron alkaline earth aluminosilicate glass composition, which is relevant to manufacturing high-performance fiberglass for high-end electronic applications. In the study, we used several techniques to trace the BtM process from room temperature up to 1400°C, namely isotherm batch heat-treatment, X-ray diffraction (XRD), hot-stage microscopy (HSM), high-temperature differential scanning calorimetry (DSC), and Fourier transform infrared (FT-IR). In the BtM process, the intermediate aluminum borate phase (Al4B2O9) between 1000 and 1100°C was identified. The formation of Al4B2O9 is explained in conjunction with the dihydroxylation of kaolin. For the first time, the potential use of the FT-IR method in studying the BtM process was demonstrated, including the dissolution of sand above 1100°C.

高硼碱土铝硅酸盐玻璃间歇-熔融转化工艺的综合研究
对一种高硼碱土铝硅酸盐玻璃组合物进行了间歇-熔体(BtM)转化工艺的综合研究,该工艺与制造用于高端电子应用的高性能玻璃纤维有关。在研究中,我们使用了几种技术,即等温间歇热处理,x射线衍射(XRD),热级显微镜(HSM),高温差示扫描量热法(DSC)和傅里叶变换红外(FT-IR),跟踪了从室温到1400°C的BtM过程。在BtM过程中,在1000 ~ 1100℃之间鉴定出硼酸铝中间相(Al4B2O9)。Al4B2O9的形成与高岭土的二羟基化作用有关。首次证明了FT-IR方法在研究BtM过程中的潜在应用,包括1100°C以上沙子的溶解。
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来源期刊
International Journal of Applied Glass Science
International Journal of Applied Glass Science MATERIALS SCIENCE, CERAMICS-
CiteScore
4.50
自引率
9.50%
发文量
73
审稿时长
>12 weeks
期刊介绍: The International Journal of Applied Glass Science (IJAGS) endeavors to be an indispensable source of information dealing with the application of glass science and engineering across the entire materials spectrum. Through the solicitation, editing, and publishing of cutting-edge peer-reviewed papers, IJAGS will be a highly respected and enduring chronicle of major advances in applied glass science throughout this century. It will be of critical value to the work of scientists, engineers, educators, students, and organizations involved in the research, manufacture and utilization of the material glass. Guided by an International Advisory Board, IJAGS will focus on topical issue themes that broadly encompass the advanced description, application, modeling, manufacture, and experimental investigation of glass.
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