{"title":"MOFs-Based Catalysts Supported Chemical Conversion of CO2","authors":"Ying Shi, Shengli Hou, Xiaohang Qiu, Bin Zhao","doi":"10.1007/s41061-019-0269-9","DOIUrl":null,"url":null,"abstract":"<p>The dramatic increase in atmospheric carbon dioxide (CO<sub>2</sub>) concentrations has attracted human attention and many strategies about converting CO<sub>2</sub> into high-value chemicals have been put forward. Metal–organic frameworks (MOFs), as a class of versatile materials, have been widely used in CO<sub>2</sub> capture and chemical conversion, due to their unique porosity, multiple active centers and good stability and recyclability. Herein, we focused on the processes of chemical conversion of CO<sub>2</sub> by MOFs-based catalysts, including the coupling reactions of epoxides, aziridines or alkyne molecules, CO<sub>2</sub> hydrogenation, and other CO<sub>2</sub> conversion reactions. The synthesized methods and high catalytic activity of MOFs-based materials were also analyzed systematically. Finally, a brief perspective on feasible strategies is presented to improve the catalytic activity of novel MOFs-based materials and explore the new CO<sub>2</sub> conversion reactions.</p>","PeriodicalId":54344,"journal":{"name":"Topics in Current Chemistry","volume":"378 1","pages":""},"PeriodicalIF":7.1000,"publicationDate":"2020-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s41061-019-0269-9","citationCount":"33","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Topics in Current Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s41061-019-0269-9","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 33
Abstract
The dramatic increase in atmospheric carbon dioxide (CO2) concentrations has attracted human attention and many strategies about converting CO2 into high-value chemicals have been put forward. Metal–organic frameworks (MOFs), as a class of versatile materials, have been widely used in CO2 capture and chemical conversion, due to their unique porosity, multiple active centers and good stability and recyclability. Herein, we focused on the processes of chemical conversion of CO2 by MOFs-based catalysts, including the coupling reactions of epoxides, aziridines or alkyne molecules, CO2 hydrogenation, and other CO2 conversion reactions. The synthesized methods and high catalytic activity of MOFs-based materials were also analyzed systematically. Finally, a brief perspective on feasible strategies is presented to improve the catalytic activity of novel MOFs-based materials and explore the new CO2 conversion reactions.
期刊介绍：
Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.
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