Junyi Peng , Qiang Zhang , Yang Zhou , Xiaohui Yang , Fang Guo , Junqiang Xu
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引用次数: 3
Abstract
Electrocatalytic CO2 reduction reaction to low-carbon alcohol is a challenging task, especially high selectivity for ethanol, which is mainly limited by the regulation of reaction intermediates and subsequent C–C coupling. A Cu-Co bimetallic catalyst with CN vacancies is successfully developed by H2 cold plasma toward a high-efficiency CO2RR into low-carbon alcohol. The Cu-Co PBA-VCN (Prussian blue analogues with CN vacancies) electrocatalyst yields methanol and ethanol as major products with a total low-carbon alcohol FE of 83.8% (methanol: 39.2%, ethanol: 44.6%) at −0.9 V vs. RHE, excellent durability (100 h) and a small onset potential of −0.21 V. ATR-SEIRAS (attenuated total internal reflection surface enhanced infrared absorption spectroscopy) and DFT (density functional theory) reveal that the steric hindrance of VCN can enhance the CO generation from *COOH, and the C–C coupling can also be increased by CO spillover on uniformly dispersed Cu atoms. This work provides a strategy for the design and preparation of electrocatalysts for CO2RR into low-carbon alcohol products and highlights the impact of catalyst steric hindrance to catalytic performance.
电催化CO2还原反应制备低碳醇是一项具有挑战性的任务,尤其是对乙醇的高选择性,这主要受到反应中间体和随后的C–C偶联的调节。利用H2冷等离子体成功地制备了一种具有CN空位的Cu-Co双金属催化剂,将CO2RR高效转化为低碳醇。Cu-Co-PBA-VCN(具有CN空位的普鲁士蓝类似物)电催化剂产生甲醇和乙醇作为主要产物,在−0.9 V vs.RHE下,总低碳醇FE为83.8%(甲醇:39.2%,乙醇:44.6%),优异的耐久性(100小时)和−0.21 V的小起始电位。ATR-SIRAS(衰减全内反射表面增强红外吸收光谱)和DFT(密度泛函理论)表明,VCN的空间位阻可以增强*COOH产生的CO,并且CO在均匀分散的Cu原子上的溢出也可以增加C–C耦合。这项工作为CO2RR转化为低碳醇产品的电催化剂的设计和制备提供了一种策略,并强调了催化剂空间位阻对催化性能的影响。
期刊介绍:
The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies.
This journal focuses on original research papers covering various topics within energy chemistry worldwide, including:
Optimized utilization of fossil energy
Hydrogen energy
Conversion and storage of electrochemical energy
Capture, storage, and chemical conversion of carbon dioxide
Materials and nanotechnologies for energy conversion and storage
Chemistry in biomass conversion
Chemistry in the utilization of solar energy