Influence of Biogenic Acid on Concrete Materials

A. Luptáková, V. Harbuláková, A. Eštoková, J. Jenčárová, Miloslav Lupták
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Abstract

Microbial sulphur cycle in sewers evocate the serious problem in the area concrete corrosion, health related aspects and odour. These problems are primarily related to the release of bacterially produced hydrogen sulphide from wastewater to the atmosphere during sewage transports that dissolves in the condensate on the sewer crown. In the event sulphur-oxidizing bacteria oxidize the dissolved hydrogen sulphide and other sulphur compounds to sulphuric acid, which corrodes the concrete. The concrete gradually expands causing cracks and ruptures, loss of strength and overall decay of concrete. The paper is focused on the investigation of the concrete specimens surface biodegradation study. From the viewpoint of concrete materials biodeterioration, mainly the bacteria sulphurand sulphide-oxidising bacteria and sulphate-reducing bacteria are important and interesting. The role of bacteria mentioned above has been linked to the generation of the biogenic sulphuric acid resulting in corrosion process by dissolution of calcium containing minerals from the concrete matrices. The penetration of the corrosion was manifested by structural changes of concrete samples. The surface structure changes were by stereomicroscopy and atomic force microscopy (AFM) investigated.
生物酸对混凝土材料的影响
下水道中的微生物硫循环引发了该地区混凝土腐蚀、健康相关方面和气味方面的严重问题。这些问题主要与污水输送过程中废水中细菌产生的硫化氢释放到大气中有关,硫化氢溶解在下水道顶部的冷凝液中。在这种情况下,硫氧化细菌会将溶解的硫化氢和其他含硫化合物氧化为硫酸,从而腐蚀混凝土。混凝土逐渐膨胀,导致裂缝和破裂、强度损失和混凝土整体腐烂。本文主要对混凝土试件的表面生物降解性进行研究。从混凝土材料的生物降解角度来看,主要是细菌硫酸盐、硫化物氧化菌和硫酸盐还原菌。上述细菌的作用与生物硫酸的产生有关,生物硫酸通过溶解混凝土基质中的含钙矿物而导致腐蚀过程。腐蚀的渗透表现为混凝土样品的结构变化。通过立体显微镜和原子力显微镜(AFM)研究了表面结构的变化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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