Size Effect in the Rate of Electrodeposition of Co–W Coatings from a Citrate Bath

IF 0.9 Q3 Engineering

Surface Engineering and Applied Electrochemistry Pub Date : 2023-09-04 DOI:10.3103/S1068375523040105

V. A. Myrzak

引用次数: 0

Abstract—

It is shown that two types of size effects in the deposition rate (i.e., a dependence of the electrodeposition rate on electrode surface area) can be observed for electrodeposition of Co–W coatings from a citrate bath: a microeffect associated with a relation between the size of microelectrodes and the diffusional current density and a macroscopic size effect related to the structure of an inducing species (a cobalt citrate complex).

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柠檬酸盐镀液中Co-W镀层电沉积速率的尺寸效应

摘要:研究表明，在柠檬酸盐镀液中电沉积Co-W涂层时，可以观察到两种类型的沉积速率尺寸效应(即电沉积速率与电极表面积的依赖关系):微电极尺寸与扩散电流密度之间的关系的微观效应和与诱导物质(柠檬酸钴配合物)结构有关的宏观尺寸效应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Surface Engineering and Applied Electrochemistry Engineering-Industrial and Manufacturing Engineering

CiteScore

1.60

自引率

22.20%

发文量

期刊介绍： Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.

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