Physico-chemical Characterization of Paint Films with Electromagnetic Properties

Abstract

Electromagnetic compatibility issues and those generated by these radiations are a major concern for electrical and electronic products, mainly in the fields of communications, information technology, transportation, security and medical services. The paper presents the way to obtain nanostructured paint/plastic/nanopowder paint systems with electromagnetic shielding properties, as well as their characterization by FTIR analysis, DSC and dielectric tests. These systems have Electro-magnetic Interference (EMI)/Electromagnetic Compatibility (EMC) and Electrostatic Discharge (ESD) applications in the manufacture of enclosures for various electronic devices and for the automotive industry. At the laboratory level, 4 non-additive experimental models (EM) coded M1-M4 and 16 additive experimental models coded M5-M20 were obtained. Revolutionary to these materials is the fact that inside they are insulating and, on the outside, they behave like a shield. The results obtained from the dielectric tests performed on the 16 additive systems showed that the samples with a maximum percentage (20 %) of metal nanopowders show the highest values of electrical conductivity. Of the two nanopowders used, that of Fe from samples M11, M12, M19 and M20 which induces the composite higher conductivities than Al nanopowders. The ATR/FTIR spectra of the two paint samples analyzed showed that they were almost identical, suggesting that the paints tested had the same basic chemical structure. DSC analysis showed that pigment paint (V2) has low thermal oxidation stability and lower decomposition temperatures than pigment-free paint (V1), therefore, V2 is less stable under usage conditions, under the influence of normal environmental factors (temperature, humidity, natural or artificial light, etc.) compared to V1.