Mild Hydrogenation of 2-Furoic Acid by Pt Nanoparticles Dispersed in a Hierarchical ZSM-5 Zeolite

Abstract

Hydrogenation of biobased compounds can add value to platform molecules obtained from biomass refining. Herein, we explore the hydrogenation of 2-furoic acid (2-furancarboxylic acid, FCA), a derivative of furfural, with H₂ generated in situ by NaBH₄ hydrolysis at ambient conditions. Nearly complete conversion of FCA was obtained with tetrahydrofuroic acid (THFA) and 5-hydroxyvaleric acid (5-HVA) as the only two reaction products over Pt nanoparticles supported on hierarchical ZSM-5. Small Pt nanoparticles (2 to 3 nm) were stabilized by ZSM-5 nanosheets. At an optimized Pt loading, the Pt nanoparticles can catalyze the hydrolysis of NaBH₄ and the subsequent hydrogenation of FCA with the assistance of Brønsted acid sites. Nanostructuring ZSM-5 into nanosheets and its acidity contributes to the stability of the dispersed Pt nanoparticles. Deactivation due to NaBO₂ deposition on the Pt particles can be countered by a simple washing treatment. Overall, this approach shows the promise of mild hydrogenation of biobased feedstock coupled with NaBH₄ hydrolysis.