Laser Promoting Oxygen Vacancies Generation in Alloy via Mo for HMF Electrochemical Oxidation

Abstract

It is well known that nickel-based catalysts have high electrocatalytic activity for the 5-hydroxymethylfurfural oxidation reaction (HMFOR), and NiOOH is the main active component. However, the price of nickel and the catalyst's lifetime still need to be solved. In this work, NiOOH containing oxygen vacancies is formed on the surface of Ni alloy by UV laser (1J85-laser). X-ray absorption fine structure (XAFS) analyses indicate an interaction between Mo and Ni, which affects the coordination environment of Ni with oxygen. The chemical valence of Ni is between 0 and 2, indicating the generation of oxygen vacancies. Density functional theory (DFT) suggests that Mo can increase the defect energy and form more oxygen vacancies. In situ Raman electrochemical spectroscopy shows that Mo can promote the formation of NiOOH, thus enhancing the HMFOR activity. The 1J85-laser electrode shows a longer electrocatalytic lifetime than Ni-laser. After 15 cycles, the conversion of HMF is 95.92%.