Comparative study of upconversion and photoacoustic measurements of Er3+/Yb3+doped La2O3phosphor under 980 nm.

IF 2.4 3区 化学 Q3 CHEMISTRY, ANALYTICAL
Minarul I Sarkar, Neeraj Kumar Mishra, Kaushal Kumar
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引用次数: 6

Abstract

The Er3+/Yb3+doped La2O3phosphor samples were synthesized by the combustion method and then photoluminescence and photoacoustic spectroscopic studies were done. Prepared samples were annealed at 800 °C, 1000 °C and 1300 °C and all samples were found in pure hexagonal phase as confirmed by XRD analysis. From FE-SEM images it is found that particle size increases with increase in annealing temperature. The frequency upconversion emission spectra of samples were recorded by exciting the sample with 980 nm diode laser and maximum emission intensity is obtained for the sample annealed at 1000 °C for 2 h. A photoacoustic cell was designed and wavelength dependent photoacoustic spectra were measured. The effect of sample storage time on radiative and non-radiative emission properties of sample was checked by measuring upconversion emission and photoacoustic spectra, simultaneously. It is observed that the emission intensity and photoacoustic signal both decreases with time. The maximum photoacoustic signal is obtained around 974 nm wavelength and it indicates its potential for photo-thermal therapy using infrared excitation.

980 nm下Er3+/Yb3+掺杂la2o3荧光粉上转换和光声测量的比较研究。
采用燃烧法制备了Er3+/Yb3+掺杂la2o3荧光粉样品,并对其进行了光致发光和光声光谱研究。制备的样品经800℃、1000℃和1300℃退火,XRD分析证实样品均为纯六方相。FE-SEM图像显示,随着退火温度的升高,晶粒尺寸增大。用980 nm二极管激光激发样品,记录了样品的频率上转换发射光谱,并在1000℃退火2 h时获得了样品的最大发射强度。设计了光声电池,测量了波长相关的光声光谱。通过测量样品的上转换发射光谱和光声光谱,考察了样品储存时间对样品辐射和非辐射发射特性的影响。发射强度和光声信号均随时间减小。最大光声信号在974 nm波长附近获得,这表明它具有利用红外激发光热治疗的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Methods and Applications in Fluorescence
Methods and Applications in Fluorescence CHEMISTRY, ANALYTICALCHEMISTRY, PHYSICAL&n-CHEMISTRY, PHYSICAL
CiteScore
6.20
自引率
3.10%
发文量
60
期刊介绍: Methods and Applications in Fluorescence focuses on new developments in fluorescence spectroscopy, imaging, microscopy, fluorescent probes, labels and (nano)materials. It will feature both methods and advanced (bio)applications and accepts original research articles, reviews and technical notes.
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