Microextrusion Printing of Hierarchically Structured Thick V2O5 Film with Independent from Humidity Sensing Response to Benzene.

Abstract

The process of V₂O₅ oxide by the combination of sol-gel technique and hydrothermal treatment using heteroligand [VO(C₅H₇O₂)_2-x(C₄H₉O)_x] precursor was studied. Using thermal analysis, X-ray powder diffraction (XRD) and infra-red spectroscopy (IR), it was found that the resulting product was VO₂(B), which after calcining at 300 °C (1 h), oxidized to orthorhombic V₂O₅. Scanning electron microscopy (SEM) results for V₂O₅ powder showed that it consisted of nanosheets (~50 nm long and ~10 nm thick) assembled in slightly spherical hierarchic structures (diameter ~200 nm). VO₂ powder dispersion was used as functional ink for microextrusion printing of oxide film. After calcining the film at 300 °C (30 min), it was found that it oxidized to V₂O₅, with SEM and atomic force microscopy (AFM) results showing that the film structure retained the hierarchic structure of the powder. Using Kelvin probe force microscopy (KPFM), the work function value for V₂O₅ film in ambient conditions was calculated (4.81 eV), indicating a high amount of deficiencies in the sample. V₂O₅ film exhibited selective response upon sensing benzene, with response value invariable under changing humidity. Studies of the electrical conductivity of the film revealed increased resistance due to high film porosity, with conductivity activation energy being 0.26 eV.