A Review on Polyethersulfone Membranes in Polar Organic Chemical Integrative Samplers: Preparation, Characterization and Innovation.

IF 4.2 2区化学 Q1 CHEMISTRY, ANALYTICAL

Critical reviews in analytical chemistry Pub Date : 2024-01-01 Epub Date: 2022-10-20 DOI:10.1080/10408347.2022.2131374

Henry MacKeown, Barbara Benedetti, Chiara Scapuzzi, Marina Di Carro, Emanuele Magi

{"title":"A Review on Polyethersulfone Membranes in Polar Organic Chemical Integrative Samplers: Preparation, Characterization and Innovation.","authors":"Henry MacKeown, Barbara Benedetti, Chiara Scapuzzi, Marina Di Carro, Emanuele Magi","doi":"10.1080/10408347.2022.2131374","DOIUrl":null,"url":null,"abstract":"<p><p>The membranes in polar organic chemical integrative samplers (POCIS) enclose the receiving sorbent and protect it from coming into direct contact with the environmental matrix. They have a crucial role in extending the kinetic regime of contaminant uptake, by slowing down their diffusion between the water phase and the receiving phase. The drive to improve passive sampling requires membranes with better design and enhanced performances. In this review, the preparation of standard polyethersulfone (PES) membranes for POCIS is presented, as well as methods to evaluate their composition, morphology, structure, and performance. Generally, only supplier-related morphological and structural data are provided, such as membrane type, thickness, surface area, and pore diameter. The issues related to the use of PES membranes in POCIS applications are exposed. Finally, alternative membranes to PES in POCIS are also discussed, although no better membrane has yet been developed. This review highlights the urge for more membrane characterization details and a better comprehension of the mechanisms which underlay their behavior and performance, to improve membrane selection and optimize passive sampler development.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2000,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Critical reviews in analytical chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/10408347.2022.2131374","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2022/10/20 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}

引用次数: 0

Abstract

The membranes in polar organic chemical integrative samplers (POCIS) enclose the receiving sorbent and protect it from coming into direct contact with the environmental matrix. They have a crucial role in extending the kinetic regime of contaminant uptake, by slowing down their diffusion between the water phase and the receiving phase. The drive to improve passive sampling requires membranes with better design and enhanced performances. In this review, the preparation of standard polyethersulfone (PES) membranes for POCIS is presented, as well as methods to evaluate their composition, morphology, structure, and performance. Generally, only supplier-related morphological and structural data are provided, such as membrane type, thickness, surface area, and pore diameter. The issues related to the use of PES membranes in POCIS applications are exposed. Finally, alternative membranes to PES in POCIS are also discussed, although no better membrane has yet been developed. This review highlights the urge for more membrane characterization details and a better comprehension of the mechanisms which underlay their behavior and performance, to improve membrane selection and optimize passive sampler development.

查看原文本刊更多论文

极性有机化学综合采样器中的聚醚砜膜综述：制备、表征和创新。

极性有机化学综合采样器（POCIS）中的膜将接收吸附剂封闭起来，防止其与环境基质直接接触。它们通过减缓污染物在水相和接收相之间的扩散，在延长污染物吸收动力学机制方面发挥着至关重要的作用。改进被动采样需要设计更好、性能更强的膜。本综述介绍了用于 POCIS 的标准聚醚砜（PES）膜的制备方法，以及评估其成分、形态、结构和性能的方法。一般来说，只提供与供应商相关的形态和结构数据，如膜类型、厚度、表面积和孔径。与在 POCIS 应用中使用聚醚砜膜有关的问题也暴露无遗。最后，还讨论了 POCIS 中 PES 的替代膜，尽管目前还没有开发出更好的膜。这篇综述强调了需要更多的膜特性细节和更好地理解其行为和性能的机制，以改进膜的选择和优化被动采样器的开发。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Critical reviews in analytical chemistry 化学-分析化学

CiteScore

12.00

自引率

4.00%

发文量

137

审稿时长

6 months

期刊介绍： Critical Reviews in Analytical Chemistry continues to be a dependable resource for both the expert and the student by providing in-depth, scholarly, insightful reviews of important topics within the discipline of analytical chemistry and related measurement sciences. The journal exclusively publishes review articles that illuminate the underlying science, that evaluate the field''s status by putting recent developments into proper perspective and context, and that speculate on possible future developments. A limited number of articles are of a "tutorial" format written by experts for scientists seeking introduction or clarification in a new area. This journal serves as a forum for linking various underlying components in broad and interdisciplinary means, while maintaining balance between applied and fundamental research. Topics we are interested in receiving reviews on are the following: · chemical analysis; · instrumentation; · chemometrics; · analytical biochemistry; · medicinal analysis; · forensics; · environmental sciences; · applied physics; · and material science.