Surveying the elimination of hazardous heavy metal from the multi-component systems using various sorbents: a review

Abstract

In this review, several adsorbents were studied for the elimination of heavy metal ions from multi-component wastewaters. These utilized sorbents are mineral materials, microbes, waste materials, and polymers. It was attempted to probe the structure and chemistry characteristics such as surface morphology, main functional groups, participated elements, surface area, and the adsorbent charges by SEM, FTIR, EDX, and BET tests. The uptake efficiency for metal ions, reusability studies, isotherm models, and kinetic relations for recognizing the adsorbent potentials. Besides, the influential factors such as acidity, initial concentration, time, and heat degree were investigated for selecting the optimum operating conditions in each of the adsorbents. According to the results, polymers especially chitosan, have displayed a higher adsorption capacity relative to the other common adsorbents owing to the excellent surface area and more functional groups such as amine, hydroxyl, and carboxyl species. The high surface area generates the possible active sites for trapping the particles, and the more effective functional groups can complex more metal ions from the polluted water. Also, it was observed that the uptake capacity of each metal ion in the multi-component solutions was different because the ionic radii of each metal ion were different, which influence the competition of metal ions for filling the active sites. Finally, the reusability of the polymers was suitable, because they can use several cycles which proves the economic aspect of the polymers as the adsorbent.