Preparation and properties of rigid polyurethane foams added with graphene oxide-hollow glass microspheres hybrid.

IF 1.8 4区 化学 Q3 POLYMER SCIENCE
Designed Monomers and Polymers Pub Date : 2021-07-14 eCollection Date: 2021-01-01 DOI:10.1080/15685551.2021.1954340
Dong Liu, Longqing Zou, Qianqian Chang, Tianyuan Xiao
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引用次数: 3

Abstract

Rigid polyurethane foam (RPUF) as a filling material that can enhance the crashworthiness of thin-walled tubes. GO-HGMS hybrid was prepared by solution blending of graphene oxide (GO) and hollow glass microspheres (HGMS). The effect of the composite on the compression properties of RPUF was investigated. The GO-HGMS hybrid was characterized by fourier transform infrared spectroscopy (FTIR), x-ray diffraction(XRD), and scanning electron microscopy (SEM). The compression test and microstructure results show that the best compression performance and the largest apparent density of the composite foam were obtained when the hybrid content was 4 wt %. In addition, the compression test results of empty tubes (ET) and foam-filled tubes (FFT) under lateral load indicate that the combination of lightweight foamed material and thin-walled tube improves the stability of thin-walled tube deformation and the ability of the structure to resist deformation. GO-HGMS/RPUF as the filling material of thin-walled tube structure greatly improves the bearing capacity and energy absorption level of ET.

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氧化石墨烯-中空玻璃微球杂化硬质聚氨酯泡沫的制备及性能研究。
硬质聚氨酯泡沫塑料(RPUF)作为填充材料,可以提高薄壁管的耐撞性。将氧化石墨烯(GO)与中空玻璃微球(HGMS)溶液共混制备了GO-HGMS杂化体。研究了复合材料对RPUF压缩性能的影响。采用傅里叶变换红外光谱(FTIR)、x射线衍射(XRD)和扫描电镜(SEM)对GO-HGMS杂化物进行了表征。压缩试验和微观组织结果表明,当杂化量为4 wt %时,复合泡沫材料的压缩性能最佳,表观密度最大。此外,空管(ET)和泡沫填充管(FFT)在侧载作用下的压缩试验结果表明,轻质泡沫材料与薄壁管的组合提高了薄壁管变形的稳定性和结构的抗变形能力。GO-HGMS/RPUF作为薄壁管结构的填充材料,大大提高了ET的承载能力和吸能水平。
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来源期刊
Designed Monomers and Polymers
Designed Monomers and Polymers 化学-高分子科学
CiteScore
3.30
自引率
0.00%
发文量
28
审稿时长
2.1 months
期刊介绍: Designed Monomers and Polymers ( DMP) publishes prompt peer-reviewed papers and short topical reviews on all areas of macromolecular design and applications. Emphasis is placed on the preparations of new monomers, including characterization and applications. Experiments should be presented in sufficient detail (including specific observations, precautionary notes, use of new materials, techniques, and their possible problems) that they could be reproduced by any researcher wishing to repeat the work. The journal also includes macromolecular design of polymeric materials (such as polymeric biomaterials, biomedical polymers, etc.) with medical applications. DMP provides an interface between organic and polymer chemistries and aims to bridge the gap between monomer synthesis and the design of new polymers. Submssions are invited in the areas including, but not limited to: -macromolecular science, initiators, macroinitiators for macromolecular design -kinetics, mechanism and modelling aspects of polymerization -new methods of synthesis of known monomers -new monomers (must show evidence for polymerization, e.g. polycondensation, sequential combination, oxidative coupling, radiation, plasma polymerization) -functional prepolymers of various architectures such as hyperbranched polymers, telechelic polymers, macromonomers, or dendrimers -new polymeric materials with biomedical applications
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