Ru/TiO₂ Nanostructured Catalysts: Synthesis, Characterization and Catalytic Activity Towards Hydrogenation of Ethyl Levulinate.

Abstract

Pristine TiO₂ and x% Ru/TiO₂ catalysts with different wt.% of Ru (x%= 1.5%, 2%, 2.5% and 3%) were synthesized using sol-gel and simple impregnation methods. Different characterization techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Scanning electron microscopy (SEM), High-resolution transmission electron microscope (HR-TEM), Inductively coupled plasma-optical emission spectrometry (ICP-OES) and Thermogravimetry/Differential thermal analysis (TG/DTA) were used to study the physicochemical and morphological properties. The XRD patterns of the as-prepared pristine TiO₂ catalyst showed high crystalline nature. The HR-TEM images revealed that the Ru nanoparticles (NPs) were evenly dispersed on the TiO₂ surface. The prepared catalysts were evaluated for their catalytic activity towards the liquid phase hydrogenation of ethyl levulinate under mild reaction conditions (ambient H2 pressure). Among the various catalysts, 2.5% Ru/TiO₂ catalyst showed the maximum catalytic activity of 79% ethyl levulinate (EL) conversion with 82% selectivity of γ-valerolactone (GVL). The recyclability test revealed that the most active 2.5% Ru/TiO₂ also showed the highest stability of the catalyst under optimized experimental conditions.