{"title":"Interfacial built-in electric-field for boosting energy conversion electrocatalysis","authors":"Hui Xu, Junru Li and Xianxu Chu","doi":"10.1039/D2NH00549B","DOIUrl":null,"url":null,"abstract":"<p >The formation of a built-in electric field (BIEF) can induce electron-rich and electron-poor counterparts to synergistically modify electronic configurations and optimize the binding strengths with intermediates, thereby leading to outstanding electrocatalytic performance. Herein, a critical review regarding the concept, modulation strategies, and applications of BIEFs is comprehensively summarized, which begins with the fundamental concepts, together with the advantages of BIEF for boosting electrocatalytic reactions. Then, a systematic summary of the advanced strategies for the modulation of BIEF along with the in-detail mechanisms in its formation are also added. Finally, the applications of BIEF in driving electrocatalytic reactions and some cascade systems for illustrating the conclusive role from the induced BIEF are also systematically discussed, followed by perspectives on the future deployment and opportunity of the BIEF design.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" 4","pages":" 441-452"},"PeriodicalIF":8.0000,"publicationDate":"2023-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"13","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanoscale Horizons","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2023/nh/d2nh00549b","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 13
Abstract
The formation of a built-in electric field (BIEF) can induce electron-rich and electron-poor counterparts to synergistically modify electronic configurations and optimize the binding strengths with intermediates, thereby leading to outstanding electrocatalytic performance. Herein, a critical review regarding the concept, modulation strategies, and applications of BIEFs is comprehensively summarized, which begins with the fundamental concepts, together with the advantages of BIEF for boosting electrocatalytic reactions. Then, a systematic summary of the advanced strategies for the modulation of BIEF along with the in-detail mechanisms in its formation are also added. Finally, the applications of BIEF in driving electrocatalytic reactions and some cascade systems for illustrating the conclusive role from the induced BIEF are also systematically discussed, followed by perspectives on the future deployment and opportunity of the BIEF design.
期刊介绍：
Nanoscale Horizons stands out as a premier journal for publishing exceptionally high-quality and innovative nanoscience and nanotechnology. The emphasis lies on original research that introduces a new concept or a novel perspective (a conceptual advance), prioritizing this over reporting technological improvements. Nevertheless, outstanding articles showcasing truly groundbreaking developments, including record-breaking performance, may also find a place in the journal. Published work must be of substantial general interest to our broad and diverse readership across the nanoscience and nanotechnology community.
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