An efficient and stable iodine-doped nickel hydroxide electrocatalyst for water oxidation: synthesis, electrochemical performance, and stability†

Abstract

The design of oxygen evolution reaction (OER) catalysts with higher stability and activity by economical and convenient methods is considered particularly important for the energy conversion technology. Herein, a simple hydrothermal method was adopted for the synthesis of iodine-doped nickel hydroxide nanoparticles and their OER performance was explored. The electrocatalysts were structurally characterized by powder X-ray diffraction analysis (P-XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDX), and BET analysis. The electrochemical performance of the electrocatalysts was assessed by cyclic voltammetry, linear sweep voltammetry, and electrochemical impedance spectroscopy. The abundant catalytic active sites, oxygen vacancies, low charge-transfer resistance, and a high pore diameter to pore size ratio of iodine-doped Ni(OH)₂ were responsible for its excellent catalytic activity, whereby OER was initiated even at 1.52 V (vs. RHE) and a 330 mV overpotential was needed to reach a 40 mV cm^?2 current density in 1 M KOH solution. The material also exhibited a low Tafel slope (46 mV dec^?1), which suggests faster charge-transfer kinetics as compared to its counterparts tested under the same electrochemical environment. It is worth noting that this facile and effective approach suggests a new way for the fabrication of metal hydroxides rich in oxygen vacancies, thus with the potential to boost the electrochemical performance of energy-related systems.