A colorimetric sensor based on catechol-terminated mixed self-assembled monolayers modified gold nanoparticles for ultrasensitive detections of copper ions

IF 4.3 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC
Siqiu Ye, Xinhao Shi, Wei Gu, Yixuan Zhang and Yuezhong Xian
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引用次数: 23

Abstract

A colorimetric sensor for Cu(II) ions has been developed based on mixed self-assembled monolayers (SAMs) modified gold nanoparticles (AuNPs). The AuNPs were modified with mixed SAMs consisting of mercaptosuccinic acid and the product of electrochemically triggered Michael addition reaction of 4-thiouracil and catechol. In the presence of Cu(II) ions, the coordination of Cu2+ to catechol-terminated AuNPs leads to aggregation-induced changes of surface plasmon resonance. The cost-effective chemical sensor allows rapid, sensitive and selective detection of Cu2+ ions, indicating its potential application in environmental field.

Abstract Image

一种基于儿茶酚端端混合自组装单层修饰金纳米粒子的比色传感器,用于铜离子的超灵敏检测
研制了一种基于混合自组装单层(SAMs)修饰金纳米颗粒(AuNPs)的Cu(II)离子比色传感器。用巯基琥珀酸和4-硫脲嘧啶与儿茶酚的电化学Michael加成反应产物组成的混合SAMs对AuNPs进行修饰。在Cu(II)离子存在下,Cu2+与儿茶酚端端AuNPs的配位导致表面等离子体共振的聚集引起的变化。具有成本效益的化学传感器能够快速、灵敏和选择性地检测Cu2+离子,表明其在环境领域的潜在应用。
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来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
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