Iodine promoted reduction of aromatic carbonyl compounds with phosphonic acid to access hydrocarbons

IF 2.1 3区化学 Q2 CHEMISTRY, ORGANIC

Tetrahedron Pub Date : 2022-05-07 DOI:10.1016/j.tet.2022.132755

Jinfeng Deng, Jing Xiao, Xiaoyi Wang, Huang Luo, Zhicheng Jia, Jie Wang

引用次数: 1

Abstract

A novel method for selective reduction of aromatic carbonyl compounds by phosphorus acid under metal-free conditions is achieved to produce the corresponding reduced products in good to excellent yields. By using H₃PO₃/I₂ system, various aromatic ketones and aldehydes could be reduced to the corresponding hydrocarbons. Diketone compounds could also be reduced to the corresponding Z-alkenes. The protocol is low-cost and easily scaled up, which provides a simple and practical approach to access corresponding hydrocarbons.

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碘促进芳香羰基化合物与膦酸还原以获得碳氢化合物

提出了一种在无金属条件下磷酸选择性还原芳香族羰基化合物的新方法，可获得收率较高的产物。在H3PO3/I2体系中，各种芳香酮类和醛类均可还原为相应的烃类。二酮类化合物也可以被还原成相应的z -烯烃。该协议成本低，易于扩展，为获取相应的碳氢化合物提供了一种简单实用的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.