Post-synthetic Fully π-Conjugated Three-Dimensional Covalent Organic Frameworks for High-Performance Lithium Storage

IF 8.2 2区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

ACS Applied Materials & Interfaces Pub Date : 2022-12-30 DOI:10.1021/acsami.2c14813

Renzeng Chen, Jingteng Zhao, Zefang Yu, Minghao Cong, Yuancheng Wang, Mingsen Wang, Guoxing Li*, Zhibo Li* and Yingjie Zhao*,

引用次数: 3

Abstract

A fully π-conjugated nitrogen-rich three-dimensional covalent organic framework (PYTRI-COF-2) containing both pyrazine and triazine units was prepared through a post-synthetic strategy. The imine linkages in the pre-prepared PYTRI-COF-1 were converted into heterocyclic quinoline by the Povarov reaction. The obtained PYTRI-COF-2 displayed high Li-ion storage capacity and excellent cycling stability when it was used as the lithium (Li)-ion battery electrode.

Abstract Image

查看原文本刊更多论文

高性能锂存储的合成后全π共轭三维共价有机框架

通过合成后策略制备了含吡嗪和三嗪的全π共轭富氮三维共价有机骨架(PYTRI-COF-2)。预先制备的PYTRI-COF-1中的亚胺键通过Povarov反应转化为杂环喹啉。所制得的PYTRI-COF-2作为锂离子电池电极，具有较高的锂离子存储容量和良好的循环稳定性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

ACS Applied Materials & Interfaces 工程技术-材料科学：综合

CiteScore

16.00

自引率

6.30%

发文量

4978

审稿时长

1.8 months

期刊介绍： ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.