High-performance activated carbon cathodes from green cokes for Zn-ion hybrid supercapacitors

IF 6.7 1区 工程技术 Q2 ENERGY & FUELS
Fuel Pub Date : 2022-02-15 DOI:10.1016/j.fuel.2021.122485
Xusheng Zhang , Xiaodong Tian , Yan Song , Jinru Wu , Tao Yang , Zhanjun Liu
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引用次数: 15

Abstract

Activated carbons (ACs) were successfully obtained through direct KOH activation method using pitch coke (PHC) and petroleum coke (PMC) as precursors. The electrochemical properties of Zn-ion hybrid supercapacitors (ZICs) assembled with the prepared ACs as electrodes were further investigated. The results showed that the PHC derived AC displayed suitable oxygen functional groups, sufficient specific surface area and favorable porosity, displaying excellent electrochemical performances with an outstanding specific capacitance of 146.4 mAh/g at 0.1 A/g, a satisfactory rate performance of 58% (from 0.1 to 10 A/g) and a high cycling stability of 95% after 5000 cycles. Furthermore, the as-obtained AC-PHC-based ZICs also delivered prominent energy output of 117 Wh/kg at 160 W/kg and 68 Wh/kg at 15.8 kW/kg.

Abstract Image

绿色焦炭制备的用于锌离子混合超级电容器的高性能活性炭阴极
以沥青焦(PHC)和石油焦(PMC)为前驱体,采用直接KOH活化法制备了活性炭(ACs)。进一步研究了以所制备的交流电为电极组装的锌离子杂化超级电容器的电化学性能。结果表明,PHC衍生的交流电具有合适的氧官能团、足够的比表面积和良好的孔隙率,具有优异的电化学性能,在0.1 A/g时比电容达到146.4 mAh/g,在0.1 - 10 A/g范围内的倍率性能达到58%,循环5000次后的循环稳定性达到95%。此外,所获得的基于ac - phc的zic在160 W/kg和15.8 kW/kg时的能量输出分别为117 Wh/kg和68 Wh/kg。
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来源期刊
Fuel
Fuel 工程技术-工程:化工
CiteScore
12.80
自引率
20.30%
发文量
3506
审稿时长
64 days
期刊介绍: The exploration of energy sources remains a critical matter of study. For the past nine decades, fuel has consistently held the forefront in primary research efforts within the field of energy science. This area of investigation encompasses a wide range of subjects, with a particular emphasis on emerging concerns like environmental factors and pollution.
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