Vibrational sum frequency spectroscopy of thin film interfaces.

IF 1.6 4区 医学 Q4 BIOPHYSICS
Biointerphases Pub Date : 2022-09-23 DOI:10.1116/6.0002085
Erin G Moloney, Md S Azam, Canyu Cai, Dennis K Hore
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引用次数: 8

Abstract

We describe a basic theoretical treatment of how film-substrate and substrate-environment (air, water, and solution) interfaces can be selectively probed by controlling the film thickness and beam angles in a visible-infrared sum frequency generation experiment. In this model, we also account for the unique interfacial environment that may have optical properties that differ from the adjacent bulk phases. We see that this affects components of the electric field that are perpendicular to the surface such as when p-polarized light is used. We then provide an example using the glass-polydimethylsiloxane-air system and model the fields at both surfaces of the polymer. This is followed by some practical considerations for setting up such experiments and some typical experimental results.

薄膜界面的振动和频率谱。
我们描述了一个基本的理论处理,如何薄膜-衬底和衬底-环境(空气,水和溶液)界面可以通过控制薄膜厚度和光束角度在可见-红外和频率产生实验中选择性地探测。在这个模型中,我们还考虑了独特的界面环境,它可能具有与相邻体相不同的光学特性。我们看到,当使用p偏振光时,这会影响垂直于表面的电场分量。然后,我们提供了一个使用玻璃-聚二甲基硅氧烷-空气系统的例子,并模拟了聚合物两个表面的场。其次是建立这类实验的一些实际考虑和一些典型的实验结果。
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来源期刊
Biointerphases
Biointerphases 生物-材料科学:生物材料
自引率
0.00%
发文量
35
期刊介绍: Biointerphases emphasizes quantitative characterization of biomaterials and biological interfaces. As an interdisciplinary journal, a strong foundation of chemistry, physics, biology, engineering, theory, and/or modelling is incorporated into originated articles, reviews, and opinionated essays. In addition to regular submissions, the journal regularly features In Focus sections, targeted on specific topics and edited by experts in the field. Biointerphases is an international journal with excellence in scientific peer-review. Biointerphases is indexed in PubMed and the Science Citation Index (Clarivate Analytics). Accepted papers appear online immediately after proof processing and are uploaded to key citation sources daily. The journal is based on a mixed subscription and open-access model: Typically, authors can publish without any page charges but if the authors wish to publish open access, they can do so for a modest fee. Topics include: bio-surface modification nano-bio interface protein-surface interactions cell-surface interactions in vivo and in vitro systems biofilms / biofouling biosensors / biodiagnostics bio on a chip coatings interface spectroscopy biotribology / biorheology molecular recognition ambient diagnostic methods interface modelling adhesion phenomena.
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