Indigoidine – Biosynthesized organic semiconductor

IF 4.1 3区工程技术 Q2 CHEMISTRY, APPLIED

Dyes and Pigments Pub Date : 2019-12-01 DOI:10.1016/j.dyepig.2019.107768

Cigdem Yumusak , Anna Jancik Prochazkova , Dogukan Hazar Apaydin , Hathaichanok Seelajaroen , Niyazi Serdar Sariciftci , Martin Weiter , Jozef Krajcovic , Yong Qin , Wei Zhang , Jixun Zhan , Alexander Kovalenko

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引用次数: 14

Abstract

Indigoidine is a blue natural pigment, which can be efficiently synthetized in E. coli. In addition to its antioxidant and antimicrobial activities indigoidine due to its stability and deep blue color can find an application as an industrial, environmentally friendly dye. Moreover, similarly to its counterpart regular indigo dye, due to its molecular structure, indigoidine is an organic semiconductor. Fully conjugated aromatic moiety and intermolecular hydrogen bonding of indigoidine result in an unusually narrow bandgap for such a small molecule. This, in its turn, result is tight molecular packing in the solid state and opens a path for a wide range of application in organic and bio-electronics, such as electrochemical and field effect transistors, organic solar cells, light and bio-sensors etc.

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靛蓝-生物合成的有机半导体

靛蓝素是一种天然的蓝色色素，可在大肠杆菌中高效合成。靛蓝素除了具有抗氧化和抗菌活性外，还因其稳定性和深蓝色而成为一种工业环保型染料。此外，与常规靛蓝染料类似，由于其分子结构，靛蓝胺是一种有机半导体。完全共轭的芳香部分和分子间的氢键使这种小分子具有异常窄的带隙。这反过来又使固态分子紧密堆积，为有机和生物电子学的广泛应用开辟了道路，如电化学和场效应晶体管、有机太阳能电池、光和生物传感器等。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dyes and Pigments 工程技术-材料科学：纺织

CiteScore

8.20

自引率

13.30%

发文量

933

审稿时长

33 days

期刊介绍： Dyes and Pigments covers the scientific and technical aspects of the chemistry and physics of dyes, pigments and their intermediates. Emphasis is placed on the properties of the colouring matters themselves rather than on their applications or the system in which they may be applied. Thus the journal accepts research and review papers on the synthesis of dyes, pigments and intermediates, their physical or chemical properties, e.g. spectroscopic, surface, solution or solid state characteristics, the physical aspects of their preparation, e.g. precipitation, nucleation and growth, crystal formation, liquid crystalline characteristics, their photochemical, ecological or biological properties and the relationship between colour and chemical constitution. However, papers are considered which deal with the more fundamental aspects of colourant application and of the interactions of colourants with substrates or media. The journal will interest a wide variety of workers in a range of disciplines whose work involves dyes, pigments and their intermediates, and provides a platform for investigators with common interests but diverse fields of activity such as cosmetics, reprographics, dye and pigment synthesis, medical research, polymers, etc.