{"title":"MOF-based materials for photo- and electrocatalytic CO2 reduction","authors":"Xiaofang Li, Qi-Long Zhu","doi":"10.1016/j.enchem.2020.100033","DOIUrl":null,"url":null,"abstract":"<div><p>Metal–organic frameworks (MOFs) have attracted much attention in photo- and electrocatalytic CO<sub>2</sub> reduction into value-added chemicals. In this review, we specially focus on the active sites of MOF-based materials to achieve visible-light absorption and efficient charge separation for photocatalytic CO<sub>2</sub> reduction, and conductivity for electrocatalytic CO<sub>2</sub> reduction, respectively. Firstly, the unique characteristics of MOF-based materials for catalytic CO<sub>2</sub> reduction are introduced. Subsequently, an overview on the recent progress and development of MOF-based materials for catalytic CO<sub>2</sub> reduction are summarized by categorizing the types of the MOF-based materials and the origin of the active sites. The active metal nodes/clusters and organic ligands can be assembled in pristine MOFs for catalytic CO<sub>2</sub><span> reduction. Diverse active species are also popular to integrate with MOFs to form MOF composites for catalytic CO</span><sub>2</sub> reduction. Besides, MOFs and their composites are intensively explored as templates and/or precursors to synthesize MOF derivatives for catalytic CO<sub>2</sub> reduction. Finally, the challenges and perspectives for further development towards MOF-based materials for CO<sub>2</sub> reduction are proposed. We have tried our best to summarize the MOF-based materials for photo- and electrocatalytic CO<sub>2</sub> reduction, aiming to inspire further ideas and exploration in this research field.</p></div>","PeriodicalId":307,"journal":{"name":"EnergyChem","volume":"2 3","pages":"Article 100033"},"PeriodicalIF":22.2000,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.enchem.2020.100033","citationCount":"173","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"EnergyChem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2589778020300087","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 173
Abstract
Metal–organic frameworks (MOFs) have attracted much attention in photo- and electrocatalytic CO2 reduction into value-added chemicals. In this review, we specially focus on the active sites of MOF-based materials to achieve visible-light absorption and efficient charge separation for photocatalytic CO2 reduction, and conductivity for electrocatalytic CO2 reduction, respectively. Firstly, the unique characteristics of MOF-based materials for catalytic CO2 reduction are introduced. Subsequently, an overview on the recent progress and development of MOF-based materials for catalytic CO2 reduction are summarized by categorizing the types of the MOF-based materials and the origin of the active sites. The active metal nodes/clusters and organic ligands can be assembled in pristine MOFs for catalytic CO2 reduction. Diverse active species are also popular to integrate with MOFs to form MOF composites for catalytic CO2 reduction. Besides, MOFs and their composites are intensively explored as templates and/or precursors to synthesize MOF derivatives for catalytic CO2 reduction. Finally, the challenges and perspectives for further development towards MOF-based materials for CO2 reduction are proposed. We have tried our best to summarize the MOF-based materials for photo- and electrocatalytic CO2 reduction, aiming to inspire further ideas and exploration in this research field.
期刊介绍:
EnergyChem, a reputable journal, focuses on publishing high-quality research and review articles within the realm of chemistry, chemical engineering, and materials science with a specific emphasis on energy applications. The priority areas covered by the journal include:Solar energy,Energy harvesting devices,Fuel cells,Hydrogen energy,Bioenergy and biofuels,Batteries,Supercapacitors,Electrocatalysis and photocatalysis,Energy storage and energy conversion,Carbon capture and storage