Synergetic integration of catalase and Fe3O4 magnetic nanoparticles with metal organic framework for colorimetric detection of phenol

Abstract

Toxic phenol pollutants pose a great threat to the environment, it is urgent to develop an efficient and recyclable method to monitor phenol. Herein, we reported the synthesis of catalase-Fe₃O₄@ZIF-8 (CAT-Fe₃O₄@ZIF-8) through a novel amino-acid-boosted one-pot embedding strategy that synergically integrated catalase and magnetic Fe₃O₄ nanoparticles with ZIF-8. As expected, CAT-Fe₃O₄@ZIF-8 exhibited enhanced catalytic activity compared with Fe₃O₄@ZIF-8, CAT@ZIF-8 and catalase. Depending on the satisfactory performance of CAT-Fe₃O₄@ZIF-8, a colorimetric detection platform for phenol based on CAT-Fe₃O₄@ZIF-8 was constructed. The corresponding detection limit was as low as 0.7 μM, and a wide linear range of 5–100 μM was obtained. Besides, CAT-Fe₃O₄@ZIF-8-based colorimetric detection platform has been verified to possess high stability and recyclability. The proposed method was proven to have potential practical applications in the field of water treatment, which would advance efficient, recyclable monitoring of water quality.