Van Thuan Le , Yasser Vasseghian , Van Dat Doan , Thi Thu Trang Nguyen , Thu-Thao Thi Vo , Ha Huu Do , Khanh B. Vu , Quang Hieu Vu , Tran Dai Lam , Vy Anh Tran
{"title":"Flexible and high-sensitivity sensor based on Ti3C2–MoS2 MXene composite for the detection of toxic gases","authors":"Van Thuan Le , Yasser Vasseghian , Van Dat Doan , Thi Thu Trang Nguyen , Thu-Thao Thi Vo , Ha Huu Do , Khanh B. Vu , Quang Hieu Vu , Tran Dai Lam , Vy Anh Tran","doi":"10.1016/j.chemosphere.2021.133025","DOIUrl":null,"url":null,"abstract":"<div><p>It is vital to have high sensitivity in gas sensors to allow the exact detection of dangerous gases in the air and at room temperature. In this study, we used 2D MXenes and MoS<sub>2</sub> materials to create a Ti<sub>3</sub>C<sub>2</sub>–MoS<sub>2</sub> composite with high metallic conductivity and a wholly functionalized surface for a significant signal. At room temperature, the Ti<sub>3</sub>C<sub>2</sub>–MoS<sub>2</sub> composite demonstrated clear signals, cyclic response curves to NO<sub>2</sub> gas, and gas concentration-dependent. The sensitivities of the standard Ti<sub>3</sub>C<sub>2</sub>–MoS<sub>2</sub> (TM_2) composite (20 wt% MoS<sub>2</sub>) rose dramatically to 35.8%, 63.4%, and 72.5% when increasing NO<sub>2</sub> concentrations to 10 ppm, 50 ppm, and 100 ppm, respectively. In addition, the composite showed reaction signals to additional hazardous gases, such as ammonia and methane. Our findings suggest that highly functionalized metallic sensing channels could be used to construct multigas-detecting sensors that are very sensitive in air and at room temperature.</p></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"291 ","pages":"Article 133025"},"PeriodicalIF":8.1000,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"46","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemosphere","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0045653521034974","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 46
Abstract
It is vital to have high sensitivity in gas sensors to allow the exact detection of dangerous gases in the air and at room temperature. In this study, we used 2D MXenes and MoS2 materials to create a Ti3C2–MoS2 composite with high metallic conductivity and a wholly functionalized surface for a significant signal. At room temperature, the Ti3C2–MoS2 composite demonstrated clear signals, cyclic response curves to NO2 gas, and gas concentration-dependent. The sensitivities of the standard Ti3C2–MoS2 (TM_2) composite (20 wt% MoS2) rose dramatically to 35.8%, 63.4%, and 72.5% when increasing NO2 concentrations to 10 ppm, 50 ppm, and 100 ppm, respectively. In addition, the composite showed reaction signals to additional hazardous gases, such as ammonia and methane. Our findings suggest that highly functionalized metallic sensing channels could be used to construct multigas-detecting sensors that are very sensitive in air and at room temperature.
期刊介绍:
Chemosphere, being an international multidisciplinary journal, is dedicated to publishing original communications and review articles on chemicals in the environment. The scope covers a wide range of topics, including the identification, quantification, behavior, fate, toxicology, treatment, and remediation of chemicals in the bio-, hydro-, litho-, and atmosphere, ensuring the broad dissemination of research in this field.