The Willgerodt-Kindler reaction on lupenone: unusual oxidative dimerization.

Farooq Biabani, Sanjay K Singh, S Kumar, Kanwal Raj, A Pathak
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引用次数: 3

Abstract

In continuation of our interest in chemical modification of triterpenoids, the Willgerodt-Kindler reaction of a lupane type triterpenoid lupenone provided a novel dimerized product 2. Formation of 2 is associated with an unusual oxidative dimerization of lupenone under Willgerodt-Kindler reaction conditions. The structure 2 was confirmed by extensive analysis of spectroscopic data including ES-MS and 2D-NMR.

lupenone的Willgerodt-Kindler反应:不寻常的氧化二聚化。
为了继续我们对三萜化合物化学改性的兴趣,一种狼烷型三萜狼烯酮的Willgerodt-Kindler反应提供了一种新的二聚体产物2。在Willgerodt-Kindler反应条件下,2的形成与一个不寻常的氧化二聚化有关。结构2被广泛的光谱数据分析证实,包括ES-MS和2D-NMR。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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