Effect of hydrogen charging time on hydrogen embrittlement of CoCrFeMnNi high-entropy alloy

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Xinfeng Li , Zheng Feng , Xiaolong Song , Yanfei Wang , Yong Zhang
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引用次数: 12

Abstract

The effect of hydrogen on mechanical properties and failure mechanism of a CoCrFeMnNi high-entropy alloy was evaluated by in/ex-situ tensile tests and electron backscatter diffraction. The results indicate that yield strength first decreases and then increases as hydrogen charging time increases, which is attributed to the competition between the hydrogen-induced softening effect and the hydrogen-enhanced twinning formation effect. The hydrogen-uncharged sample shows the micro-void coalescence failure mechanism, whereas hydrogen-assisted cracking of the alloy initiates from grain boundaries and slip bands caused by plasticity-mediated decohesion mechanism. Crystallographic analysis demonstrates that {110}//ND grains and {001}//ND-{111}//ND grain boundaries are vulnerable to hydrogen embrittlement.

充氢时间对CoCrFeMnNi高熵合金氢脆的影响
通过原位/非原位拉伸试验和电子背散射衍射研究了氢对CoCrFeMnNi高熵合金力学性能的影响及破坏机制。结果表明:随着充氢时间的延长,屈服强度先减小后增大,这是由于氢诱导软化效应和氢增强孪晶形成效应相互竞争的结果;未充氢试样表现为微空洞聚结破坏机制,而充氢试样则表现为塑性脱黏机制引起的晶界和滑移带开裂。晶体学分析表明,{110}//ND晶界和{001}//ND-{111}//ND晶界容易发生氢脆。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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